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US 4,046,816 AGranted
Process for preparing resorcinol monoethers
AssigneeHoechst Aktiengesellschaft
InventorWerner Heinrich Muller
Life of this patent
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Abstract
Process for the preparation of resorcinol monoalkyl ethers by dehydrogenizing 3-alkoxycyclohexene-(2)-ones in the liquid or gaseous phase.
Claims1
A process for the preparation of resorcinol monoalkyl ethers of the general formula I and II:
- ##STR15## wherein the radicals R.sub.1 to R.sub.4 may be the same or different and each represents a hydrogen, straight chain, branched or cyclic aliphatic radical or an aryl group or araliphatic radical and the radicals R.sub.5 and A stand for straight chain, branched or cyclic aliphatic radical or araliphatic radical which comprise dehydrogenating in a liquid phase using as a liquid a triethylene glycol dialkyl ether or a diethylene glycol dialkyl ether having alkyl groups of up to 6 carbon atoms, at a temperature from 160.degree. to 350.degree. C. in the presence of a catalyst containing noble metals of subgroup VIII of the Periodical Table 3-alkoxycyclohexene-(2)-ones of the general formulae I' and II' ##STR16## wherein R.sub.1 to R.sub.5 and A have the aforesaid meaning.
Dependencies are inferred from the claim text.