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US 4,046,745 AGranted
Preparation of functional polymers
AssigneePhillips Petroleum Company
InventorsCharles M. Selman, Carl A. Uraneck
Life of this patent
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Abstract
Lithium salts of monohydroxyalkyl-substituted conjugated alkadienes are employed as comonomers in the polymerization of conjugated dienes, or conjugated dienes with monovinyl aromatic compounds, to produce polymers containing hydroxy functionality. The hydroxy functionality permits efficient curing.
Claims23
A process for preparing a cured polymer which comprises the steps of:
- a. copolymerizing at least one conjugated diene, or at least one conjugated diene with at least one monovinyl-substituted aromatic hydrocarbon, with a minor effective amount for a lithium salt of a monohydroxyalkyl-substituted conjugated alkadiene as comonomer, under solution polymerization conditions of temperature and pressure and employing an effective amount of a lithium-based initiator, thereby preparing a copolymer, wherein said lithium salt of a monohydroxyalkyl-substituted conjugated alkadiene represents the reaction product of a monohydroxyalkyl-substituted conjugated alkadiene with lithium or with a hydrocarbyllithium compound, and wherein said monohydroxyalkyl-substituted conjugated alkadiene is represented by the formula ##STR4## wherein Q is R or a monohydroxyalkyl group represented by ##STR5## wherein each R is hydrogen or is an alkyl, cycloalkyl, aryl, or combination radical;
- each R' is hydrogen, methyl, or ethyl;
- n is an integer of 1 to 3;
- such that said monohydroxyalkyl-substituted conjugated alkadiene contains 1 hydroxyalkyl group per molecule;
- b. treating said copolymer from said step (a) with an effective amount of an alkylene oxide;
- and
- c. curing the alkylene oxide-treated copolymer with a polyisocyanate curing system.
4 more elements
Dependencies are inferred from the claim text.