Removal of antimony from industrial streams
AssigneeRohm and Haas Company
InventorsVirginia L. Cunningham, James S. Clovis, Marvin J. Hurwitz
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Abstract
A novel process is described for the removal and/or recovery of dissolved antimony from an industrial stream, such as a waste stream, using a strong acid and/or a strong base ion exchange resin, in the hydrogen and hydroxyl forms respectively, to adsorb the antimony.
Claims11
A process for removing antimony from an industrial stream containing a minor amount of solubilized antimony which comprises passing said industrial stream into contact with at least one ion exchange resin selected from strong acid cation exchange resin in the hydrogen form to remove antimony present as, or convertible to, the cationic form and strong base anion exchange resin in the hydroxyl form to remove antimony present as, or convertible to, the anionic form.
A process for removing antimony from an acidic industrial stream containing the same in minor concentrations which comprises passing said industrial stream through a bed of strong acid cation exchange resin in the hydrogen form until the ion exchange capacity of the resin is largely exhausted by exchange with antimony and thereafter eluting the antimony from the resin with a strong base.
A process for removing antimony from an industrial stream containing the same in minor concentrations which comprises passing said industrial stream through a bed of strong base anion exchange resin in the hydroxyl form until the ion exchange capacity of the resin is largely exhausted by exchange with antimony.
A process for recovering antimony from an industrial stream containing a minor amount of solubilized antimony which comprises contacting such industrial stream in series with both strong acid and strong base ion exchange resins in their hydrogen and hydroxyl forms, respectively, to remove essentially all of the antimony from the stream and thereafter eluting the antimony from the strong acid and strong base resins, precipitating the antimony with acid, and recovering the antimony trioxide by filtration.
Dependencies are inferred from the claim text.