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US 4,045,458 AGranted
Process for preparing triarylmethane derivatives
AssigneeKanzaki Paper Manufacturing Co., Ltd.
InventorsMitsura Kondo, Kiyoshi Yasui, Makoto Miyake, Hiroshi Iwasaki, Tetsuo Shiraishi
Life of this patent
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Abstract
A process is described for preparing triarylmethane derivatives of a high purity in an extremely high yield from 3-phenylphthalide derivatives and aniline derivatives or indole derivatives with Friedel-Crafts type catalyst or Friedel-Crafts type catalyst and an oxidizing agent.
Claims7
A process for preparing a triarylmethane derivative having the general formula:
- ##STR211## wherein each R.sub.1 and R.sub.2 represents at least one of hydrogen, halogen, a nitro group, an alkyl group, a substituted alkyl group, an amino group, a substituted amino group, a hydroxyl group, a substituted hydroxyl group, a thiohydroxyl group or a substituted thiohydroxyl group, each R.sub.3 and R.sub.4 represents hydrogen, a substituted or unsubstituted alkyl group, a cycloalkyl group, a substituted or unsubstituted aralkyl group, substituted or unsubstituted aryl group, or a substituted unsaturated alkyl group, R.sub.5 represents at least one of hydrogen, halogen, an alkyl group, a nitro group, a substituted or unsubstituted amino, group, substituted or unsubstituted hydroxyl group, or a substituted or unsubstituted thiohydroxyl group which comprises reacting a 3-phenylphthalide derivative having the general formula:
- ##STR212## wherein R.sub.1 and R.sub.2 are the same as described hereinabove, with an aniline derivative having the general formula:
- ##STR213## wherein R.sub.3, R.sub.4 and R.sub.5 are the same as hereinabove defined, in the presence of a Friedel-Crafts type catalyst.
Dependencies are inferred from the claim text.