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US 4,045,381 AGranted
Organosilicone polymers
AssigneeUnion Carbide Corporation
InventorsBela Prokai, Bernard Kanner
Life of this patent
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Abstract
Cyano-modified polysiloxane-polyoxyalkylene block copolymers that contain a trifunctional RSiO3/2 siloxy unit, as well as, a process for producing flexible polyether urethane foam wherein said copolymers are employed as the foam stabilizing component.
Claims26
A polysiloxane-polyoxyalkylene block copolymer having the average formula
- [RSiO3/2].sub.t (R.sub.2 SiO).sub.w (R(R.sup.1)SiO).sub.z [(C.sub.n H.sub.2n O).sub.p R.sup.2 ].sub.v
- wherein:
- R represents a momovalent hydrocarbon radical having from 1 to 10 carbon atoms;
- R.sup.1 represents a cyano-substituted radical of the formula --(O).sub.a R.sup.3 CN wherein R.sup.3 is a bivalent alkylene radical having from 2 to 6 carbon atoms or a bivalent alkyleneoxyalkylene radical having from 4 to 12 carbon atoms, and a has a value of 0 or 1;
- R.sup.2 is a monovalent hydrocarbon radical having from 1 to 12 carbon atoms;
- t has an average value of about 0.8 to about 4;
- w has an average value of about 3 to about 100,
- z has an average value of about 3 to about 20;
- n has a value of from 2 to 4 provided that about 20 to about 65 weight percent of the oxyalkylene units of the polyoxyalkylene chain, (C.sub.n H.sub.2n O).sub.p, is constituted of oxyethylene units;
- p has an average value such that the average molecular weight of the polyoxyalkylene chain is from about 800 to about 6000, and
- v has an average value of about 2 to about 4.
8 more elements
Dependencies are inferred from the claim text.