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US 4,045,377 AGranted
Cationic polymer prepared from dicyandiamide, a polyamide, a dialkylamine, and an epoxide
AssigneeHercules Incorporated
InventorStephen C. Pearson
Life of this patent
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Abstract
Cationic polymers which are useful as flocculants are prepared by reacting (a) a condensation polymer prepared from dicyandiamide and a polyalkylenepolyamine, (b) a dialkylamine, and (c) a difunctional epoxide.
Claims12
A process for the preparation of a water-soluble cationic polymer comprising:
- a. reacting and polyalkylenepolyamine having the formula ##STR4## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 hydroxyalkyl;
- R.sub.2 is independent of the other R.sub.2 and is an alkylene radical having from 2 to 6 carbon atoms and x is an integer of 1 to 5 and dicyandiamide in a mole ratio of polyalkylenepolyamine to dicyandiamide of from about 1.2/1 to about 1/1.2 until reaction is substantially complete whereby a condensation polymer is produced,
- b. forming an aqueous solution of the condensation polymer of step (a),
- c. admixing dialkylamine having the formula ##STR5## wherein R.sub.3 is independent of the other R.sub.3 and is a C.sub.1 -C.sub.3 alkly, and the aqueous solution of condensate polymer of step (b) in a mole ratio of dialkylamine to the equivalent molecular weight of the repeating unit of the condensation polymer of from about 20/1 to about 2/1,
- d. admixing the mixture of step (c) with difunctional epoxide, the mole ratio of difunctional epoxide to dialkylamine being from about 2/1 to about 1/1,
- e. reacting the resulting admixture at a temperature of from about 50.degree. C. to about 80.degree. C., said reaction being continued until the viscosity of the resultant cationic polymer is in the range of from about 40 centipoises to about 250 centipoises, viscosity of the cationic polymer being measured in water as a 40% by weight solution at 25.degree. C., and
- f. terminating the reaction of step (e).
4 more elements
Dependencies are inferred from the claim text.