A method for preparing a compact soil modifier comprising from 80 to 95% by weight of a mixture of ferric oxide and ferric sulphate in an oxide/sulphate weight ratio of from 0.2:1 to 2:1, which comprises calcining at a temperature of from 500.degree. to 600.degree. C, in the presence of an oxidizing gas, a material comprising as a main component hydrated ferrous sulphate with an average number of molecules of crystallization of from 1 to 5, for a period sufficient to convert from 80 to 95% by weight of said hydrated sulphate into ferric oxide and ferric sulphate, said material being obtained by the partial dehydration of a waste material consisting essentially of ferrous sulphate heptahydrate obtained in the manufacture of titanium dioxide from ilmenites or ilmenite slags by the sulphate process.