Stampable thermoplastic sheet reinforced with multilength fiber
AssigneeAllied Chemical Corporation
InventorLeon Segal
Life of this patent
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Abstract
Reinforced thermoplastic polymer composite sheets are formable into smooth, shaped objects in a rapid stamping process in a cool mold when pre-heated outside of the mold. The characterizing constituents of the composite sheet are: (1) thermoplastic resin, (2) relatively short reinforcing fibers, (3) relatively long or continuous glass fiber, and (4) a particulate loading agent. This four-component system, laminated together, produces sheets having excellent formability, mechanical properties, uniformity and in particular surface smoothness not heretofore obtainable, and are simple to fabricate continuously.
Claims10
A smooth surfaced thermoplastic composite sheet having an average surface roughness height under 500 microinches comprising, in percent by weight of the total composite,
- a. from about 25 to 65% of a synthetic thermoplastic resin,
- b. from about 25 to 40% of a particulate filler,
- c. from about 15 to 45% of short glass reinforcing fibers having a length of not greater than about 0.85 inch, at least 50% of said fibers being aligned substantially parallel to the plane of the sheet, and
- d. from about 2% to 10% of long glass fibers having a length of about 11/2 inches to continuous and being substantially below the exterior surface of the composite sheet.
A process for producing a smooth surfaced thermoplastic composite sheet formable into smooth, shaped objects in a rapid stamping process in a cool mold when preheated outside of the mold, which process comprises:
- a. forming a surface layer comprising, by weight based upon the total weight of the composite, from about 25 to 65% of a synthetic thermoplastic resin, from about 25 to 40% of a particulate filler, and from about 15 to 45% of short glass fiber reinforcement having a fiber length of not greater than about 0.85 inch, said fibers being aligned substantially parallel to the plane of said layer, and
- b. adhering thereto, with said thermoplastic resin as a binder, under heat and pressure a substrate comprising a glass mat formed of fiber lengths of at least 1.5 inches in length, said mat being present in said composite in an amount of about 2 to 10% by weight of the total composite and said glass fibers being substantially below the exterior surface of said composite sheet.
In a method of forming shaped articles having intricate protrusions and recesses from a thermoplastic stampable sheet containing long glass fiber reinforcement, the improvement to prevent bridging of the glass fiber reinforcement and to enhance the formation of said protrusions and recesses comprising combining with about 2 to 10% by weight of the long glass fiber reinforcement, which has a fiber length in excess of 1.5 inches and about 25 to 65% by weight of the thermoplastic resin, from about 15 to 45% of a relatively short glass fiber reinforcement wherein said short glass fiber has a length not in excess of 0.85 inch, said short glass fiber reinforcement functioning to substantially force said long glass fiber into said protrusions and recesses during the forming steps, said short fibers being substantially parallel to the plane of the sheet, and from about 25 to 40% by weight of an inert, finely comminuted particulate filler, said long glass fibers being substantially below the exterior surface of said sheet.
Dependencies are inferred from the claim text.