Process for the manufacture of highly elastic soft polyurethane foams
AssigneeTh. Goldschmidt AG
InventorsHelmut Lammerting, Rolf-Dieter Langenhagen, Gerd Rossmy, Peter Zaske
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Abstract
In the disclosed foaming process for manufacturing soft polyurethane foams on the basis of polyethers containing at least two hydroxy groups, the foaming is carried out in the presence of selected low-molecular weight, low-viscosity methylpolysiloxanes which do not cause disorders in the boundary regions of the foam or shrinkage.
Claims13
In a process of producing cold cure soft polyurethane foams, wherein polyethers having at least two hydroxy groups per molecule, water and organic polyisocyanate are foamed in the presence of catalysts, the foaming system optionally comprising cross-linkers, blowing agents and/or other auxiliaries, the improvement which comprises adding to the foaming system organopolysiloxane of the formula I ##STR4## wherein
- R.sup.1 represents the same of different unsubstituted or substituted hydrocarbon groups which are devoid of groups that have a tendency to enter addition reactions with isocyanate;
- R.sup.2 has the same meaning as R.sup.1 or is OR.sup.3, wherein
- R.sup.3 represents alkyl, aryl, alkaryl or [C.sub.m H.sub.2m O].sub.p R.sup.4,
- R.sup.4 being lower alkyl,
- m = 2 to 4 and
- p being selected such that the mole weight of the total R.sup.3 group does not exceed 400;
- and
- n = 2-10 and wherein essentially none of the individual components of the mixtures possess a value of n>10,
- the amount of the compound of formula I being between about [0,003] 0.003 to 2% by weight calculated on the amount of polyether in the foaming system.
Dependencies are inferred from the claim text.