Apparatus for the production of sulfur from mixtures of hydrogen sulfide and fixed nitrogen compounds
AssigneeThe Ralph M. Parsons Company
InventorDavid K. Beavon
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AssigneeThe Ralph M. Parsons Company
InventorDavid K. Beavon
Estimating the term…
To permit the processing of hydrogen sulfide-fixed nitrogen compound feed streams, e.g. H.sub.2 S--NH.sub.3 mixtures without causing plugging problems usually encountered in a Claus sulfur plant due to the formation of solid nitrogen sulfur salts, a first hydrogen sulfide feed containing substantial quantities of fixed nitrogen compounds, a portion of a second hydrogen sulfide feed essentially free of fixed nitrogen compounds and air are combined in a first thermal reaction zone where the amount of oxygen present is sufficient to achieve a high flame temperature for essentially complete conversion of the fixed nitrogen compounds to inert nitrogen, but insufficient to consume all of the hydrogen sulfide present. The effluent of the first reaction zone is combined with the balance of the second hydrogen sulfide feed in a second thermal reaction zone where hydrogen sulfide and sulfur dioxide react to form sulfur. After sulfur condensation, the gas stream is passed to the conventional catalytic Claus conversion stage zone. There is also provided an improved reaction furnace for use in the process.
In a thermal reactor for use in sulfur production consisting of a thermal reactor containing two thermal reaction zones in series, wherein the first thermal reaction zone has an inlet for feeding a first hydrogen sulfide feed and a source of oxygen thereto and wherein at least part of the hydrogen sulfide is converted to sulfur dioxide and wherein the second reaction zone has means associated therewith for feeding a second hydrogen sulfide feed thereto and wherein a portion of the formed sulfur dioxide reacts with hydrogen sulfide in the second thermal reaction zone to form sulfur, the improvement which comprises separating the first and second thermal reaction zones by a partition formed of a first transversely positioned planar apertured wall spaced from a second transversely positioned planar apertured wall, said planar walls being joined at their periphery to the external walls of said thermal reactor and extending radially inwardly therefrom, the first planar apertured wall serving a radiating surface to maintain a higher temperature in the first thermal reaction zone than the second thermal reaction zone, the respective apertures of said planar walls being interconnected by a gas flow conduit of a cross-sectional area which provides turbulent gas flow between said first and second thermal reaction zones, said partition being provided with means to introduce the second hydrogen sulfide feed into the gas flow conduit in the thermal reactor for turbulent mixing with the gas stream flowing from the first thermal reaction zone to the second reaction zone.
A thermal reactor for use in sulfur production which comprises:
Dependencies are inferred from the claim text.