US 4,036,890 A · Preparation of organic hydroperoxides

Abstract

Improvement in the known process for producing organic cyclic hydroperoxides, which process includes oxidizing a compound of the formula ##STR1## wherein Ar is an aromatic or saturated cycloaliphatic radical and each R is an aliphatic hydrocarbon radical or a hydrogenated bicyclic terpene hydrocarbon hydroperoxide with an oxygen-containing gas at a temperature of about 80.degree.-150.degree. C under a pressure of about atmospheric up to about 10 atms., wherein the product, when produced by this process, has an improved activity on the catalysis of olefin polymerization if the oxidation reaction is halted at the point where the produced hydroperoxide has a concentration in the reaction mass of about one to less than 5%.

Claims9

Dependent claims

In the production of organic cyclic hydroperoxides which comprises oxidizing a compound selected from the group consisting of compounds of the formula:

##STR3## wherein Ar is a member selected from the group consisting of phenyl, cyclohexyl and cycloheptyl, which can be substituted by C.sub.1-5 alkyl and each R is an aliphatic hydrocarbon radical, and compounds of the group consisting of carane, pinane, p-menthane and camphane with an oxygen-containing gas at a temperature of about 80.degree. to 150.degree. C. and a pressure of about atmospheric up to about 10 atmospheres;
the improvement which comprises halting said oxidation when the concentration of produced hydroperoxide reaches about 1 to less than 5% by weight in the reaction mixture, and recovering said cyclic hydroperoxide.

Dependencies are inferred from the claim text.

Preparation of organic hydroperoxides

Life of this patent

Preparation of organic hydroperoxides

Life of this patent

Abstract

Claims9