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US 4,035,430 AGranted
Conversion of methanol to gasoline product
AssigneeMobil Oil Corporation
InventorsFrancis G. Dwyer, Francis V. Hanson, Albert B. Schwartz
Life of this patent
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Abstract
The conversion of methanol to gasoline boiling products in a plurality of sequentially arranged catalyst beds comprising a dehydration catalyst followed by a special class of crystalline zeolite conversion catalyst is described wherein the dehydration catalyst life is prolonged and durene formed in the process is recycled to the zeolite catalyst conversion step.
Claims11
In a method for converting methanol to gasoline boiling products in a plurality of sequentially arranged catalyst beds which comprises,
- effecting a catalytic restructuring of the methanol feed to an ether rich product in at least one catalyst contact zone under selected temperature conditions,
- effecting a catalytic restructuring of the ether rich product to form aromatics and isoparaffins boiling in the gasoline boiling range in at least one other catalyst contact zone employing a crystalline zeolite of the class represented by ZSM-5 crystalline zeolite, the improvement comprising
- effecting control of the exothermic temperature rise in any one bed of crystalline zeolite catalyst not to exceed about 50 degrees F. by employing with the ether rich feed one or a combination of heat dissipating materials selected from the group consisting of C.sub.5 and lower boiling hydrocarbons, a cooled methanol stream alone or in combination with a water free cool ether product fraction or a cool durene rich product fraction of the process.
Dependencies are inferred from the claim text.