Antistatic agents for melt-formed polymers
AssigneeBASF Wyandotte Corporation
InventorsEugene A. Weipert, Charles F. Deck
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Abstract
Permanent antistatic properties are imparted to melt-formed polymers by the incorporation therewith of a polymer composition prepared by reacting a hydrogen-reactive compound with an alkylene oxide adduct of a nitrogen-containing compound. Further, the polymer composition may be capped to minimize reaction with the melt-formed polymer.
Claims7
An antistatic agent prepard by the reaction in a mole ratio of (a) to (b) of from about 0.5:1.0 to 1.0:1.0 at a temperature from about 60.degree. to 160.degree. C. for a period of from about 1 to about 4 hours of:
- a. an alkyl ester of a dicarboxylic acid represented by the formula:
- R"OOC--R--COOR'
- wherein R is the organic portion of the dicarboxylic acid selected from the group consisting of oxalic, malonic, succinic, glutaric, adipic, pimelic, suberic, azelaic, sebasic, phthalic, isophthalic, terephthalic, and hydrogenated terephthalic, and R' and R" are, each, individually, alkyl having from one to four carbon atoms, or hydroxyalkyl having from two to four carbon atoms with
- b. an alkylene oxide adduct of a nitrogen-containing compound selected from the group consisting of alkanolamine, alkanolpolyamine, alkylene polyamine, polyalkylenepolyamine, aromatic polyamine and .alpha. -olefin oxide adducts thereof, said alkylene oxide selected from the group consisting of ethylene oxide or a mixture of ethylene oxide and a lower alkylene oxide having from three to four carbon atoms, said mixture comprising at least 25% by weight of ethylene oxide, said adduct having a molecular weight of from 1,000 to 40,000 and comprising from 60% to 99% by weight of alkylene oxide.
The antistatic agent of claim 2 wherein (a) is dimethylterephthalate.
Dependencies are inferred from the claim text.