Method of producing optically transparent ceramics
AssigneeHitachi, Ltd.
InventorsKatsuki Miyauchi, Iwao Matsuyama, Gyozo Toda
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AssigneeHitachi, Ltd.
InventorsKatsuki Miyauchi, Iwao Matsuyama, Gyozo Toda
Estimating the term…
There is provided a method of producing a ceramic represented by the general formula of ABO.sub.3, wherein A includes Pb and at least one element selected from the group consisting of Ba and Sr and B is either of Zr or both of Zr and Ti, by hot-pressing a complex oxide obtained by calcining the mixture of the oxides of A and B characterized by that a solid solution of the oxides of Ba and/or Sr and the oxide of the element constituting B, such as BaTiO.sub.3, SrZrO.sub.3 or (Ba, Sr)ZrO.sub.3, is used as the starting oxides of Ba and/or Sr, and that the starting material contains PbO in an amount of 3 - 20 mol% in excess of that calculated for the objective composition of the final product. Ceramics produced by the method of the present invention have ferroelectric properties and are optically transparent.
A method of producing an optically transparent ceramic having a perovskite-type crystal structure and represented by the general formula ABO.sub.3, wherein the component A consists of Pb and at least one other element selected from the group consisting of Ba and Sr and the component B is selected from the group consisting of Zr or a mixture of Zr and Ti, said method comprising forming a powdery mixture of lead oxide, a solid solution which consists of either barium oxide or strontium oxide or both with an oxide of at least one of the elements of component B, calcining the resultant powdery mixture to form a complex oxide powder, molding said complex oxide powder under pressure to yield a green compact, and hot-pressing said green compact under a pressure greater than 70 kg/cm.sup.2 at a temperature of 1200.degree.-1500.degree. C. for more than 2 hours in an oxygen atmosphere.
A method for producing an optically transparent ceramic having a perovskite-type crystal structure and represented by the general formula of ABO.sub.3, wherein A consists of Pb and at least one other element selected from the group consisting of Ba and Sr, and B, is selected from the group consisting of Zr or a mixture of Zr and Ti, said method comprising
A method for producing an optically transparent ceramic having a perovskite-type crystal structure and represented by the general formula of ABO.sub.3, wherein A consists of Pb and at least one other element selected from the group consisting of Ba and Sr, and B, is selected from the group consisting of Zr or a mixture of Zr and Ti, said method comprising
A process for producing an optically transparent ceramic having a perovskite-type crystal structure and represented by the general formula ABO.sub.3, wherein component A includes Pb and at least one element selected from the group consisting of Ba and Sr and component B includes Zr or both Zr and Ti, said method comprising:
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