Polyurethane intermediates and products and methods of producing same from lignin
AssigneeResearch Corporation
InventorsWolfgang Gerhard Glasser, Oscar Hsien-Hsiang Hsu
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AssigneeResearch Corporation
InventorsWolfgang Gerhard Glasser, Oscar Hsien-Hsiang Hsu
Estimating the term…
Polycarboxy-oxyalkylene polyester-ether polyol intermediates useful in the production of polyurethane products and methods of making the intermediates and polyurethane products are described. The polyol intermediates are made from lignin by reacting lignin with maleic anhydride, substituted maleic anhydride, or mixtures thereof to form carboxylated lignin maleic anhydride copolymers. These copolymers are then reacted with an oxyalkylating medium with or without prior hydrolysis to form the polyol intermediates. These polyester-ether polyol intermediates are then reacted with an isocyanate medium having an isocyanate with at least 2 NC0 groups per molecule to produce polyurethane products with or without simultaneous foaming.
A method for the preparation of a polycarboxyoxyalkylene polyester-ether polyol from lignin comprised of the following steps:
A polycarboxy-oxyalkylene polyester-ether polyol formed by the sequential reaction process comprising the steps of first reacting a lignin with a maleic anhydride, substituted maleic anydride, or mixtures thereof to form a lignin-maleic anydride copolymer, and then reacting said copolymer with an oxyalkylating medium.
Dependencies are inferred from the claim text.