Azo dye with a 2,6-diamino-5-cyano-or-5-carbamoyl-pyridine coupling component
AssigneeBASF SE
InventorsJohannes Dehnert, Gunther Lamm
Life of this patent
Estimating the term…
Abstract
A dye of the formula ##STR1## wherein D is the radical of a diazo component, especially phenyl, phenylazophenyl, benzthiazolyl, benzisothiazolyl, thienyl, thiazolyl, thiadiazolyl and substituted derivatives thereof, R is hydrogen or alkyl of 1 to 7 carbon atoms, X is cyano or carbamoyl, A is a hydrocarbon radical, the two A's together with the nitrogen form a saturated heterocyclic ring, and A.sup.1 is hydrogen or a hydrocarbon radical. The dyes are eminently suitable for coloring synthetic fibers, particularly polyesters, brilliant shades.
Claims14
A dye of the formula ##STR160## where D.sup.1 is phenyl substituted by chlorine, bromine, trifluoromethyl, methyl, ethyl, methoxy, nitro, cyano, methylsulfonyl, ethylsulfonyl, phenylsulfonyl, carbalkoxy of a total of 2 to 5 carbon atoms, carbo-.beta.-alkoxyethoxy, said alkoxy having 1 to 4 carbon atoms or N,N-dialkyl-substituted sulfamoyl, said alkyl having 1 to 3 carbon atoms;
- phenylazophenyl;
- phenylazophenyl substituted by methyl, chlorine, bromine or nitro;
- benzthiazolyl;
- benzthiazolyl substituted by nitro, cyano, methylsulfonyl or ethylsulfonyl;
- benzisothiazolyl substituted by chlorine, bromine, cyano or nitro;
- thiazolyl substituted by cyano or nitro;
- thienyl substituted by methyl, cyano, nitro or carbalkoxy of a total of 2 to 5 carbon atoms;
- or thiadiazolyl substituted by phenyl, methyl, chlorine, bromine, methylmercapto, ethylmercapto or alkoxycarbonylethylmercapto, said alkoxy having 1 to 4 carbon atoms;
- R.sup.1 is hydrogen or alkyl of 1 to 3 carbon atoms;
- X is carbamoyl or cyano;
- A.sup.3 is hydrogen, alkyl of 1 to 8 carbon atoms;
- alkyl of 2 to 8 carbon atoms substituted by hydroxy, OCHO, OCOCH.sub.3, hydroxyalkoxy of 2 to 4 carbon atoms, cyano, alkoxy of 1 to 8 carbon atoms, phenoxy or phenyl;
- cyclohexyl;
- norbornyl;
- phenyl;
- .beta.-hydroxy-.beta.-phenylethyl;
- or (CH.sub.2).sub.3 (OC.sub.2 H.sub.4).sub.m OT and T is alkyl of 1 to 4 carbon atoms, benzyl or phenyl, m is 1 to 2,
- each A.sup.2, which can be the same or different, is alkyl of 1 to 4 carbon atoms, hydroxyalkyl of 2 or 3 carbon atoms, alkoxyalkyl of 1 to 4 carbon atoms in the alkoxy and 2 or 3 carbon atoms in the alkyl, cyclohexyl or phenyl and ##STR161## is pyrrolidino, piperidino, morpholino, hexamethyleneimino, piperazino, N-methylpiperazino or N-.beta.-hydroxyethylpiperazino.
The dye of the formula ##STR170##
The dye of the formula ##STR171##
The dye of the formula ##STR172##
The dye of the formula ##STR173##
The dye of the formula ##STR174##
The dye of the formula ##STR175##
The dye of the formula ##STR176##
Dependencies are inferred from the claim text.