Monoazo dyestuffs containing an N-.beta.-1,2,3-triazolylethyl anilino coupling component
AssigneeBayer Aktiengesellschaft
InventorsGerhard Wolfrum, Heinrich Gold
Life of this patent
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Abstract
Azo dyestuffs of the formula ##SPC1## Wherein A stands for the residue of the diazo component, R stands for hydrogen or methyl, R.sub.1 is a non-ionic substituent, M is a number from 0 to 2, R.sub.2 stands for hydrogen or for an aliphatic, araliphatic, or aromatic radical, R.sub.3 and R.sub.4 are independently selected from the group consisting of hydrogen, alkyl, alkoxy methyl, aryl, carboxy, carboalkoxy, said dyestuff being free of sulphonic acid groups and being adapted for use in dyeing and printing synthetic fiber materials. The quaternary salts of the dyestuffs are also adapted for use in such dyeing and printing.
Claims11
An azo dyestuff selected from the group consisting of ##SPC20##
- wherein R stands for hydrogen or methyl;
- R.sub.1 is a member selected from the group consisting of chloro, bromo, lower alkyl, trifluoro lower alkyl, lower alkoxy, and acetylamino;
- m is an integer from 0 to 2;
- R.sub.2 stands for hydrogen, lower alkyl, or substituted lower alkyl, wherein the substituents are selected from the group consisting of cyano and ethoxy carbonyl;
- R.sub.3 and R.sub.4 are independently selected from the group consisting of hydrogen, lower alkyl, lower alkoxy methyl, phenyl, chlorophenyl, bromophenyl, lower alkyl phenyl, carboxylic acid, carbolower alkoxy;
- R.sub.5 is selected from the group consisting of lower alkyl and benzyl;
- A is selected from the group consisting of phenyl, substituted phenyl, thiazol (1,3)-2-yl, 5-nitro thiazol (1,3)-2-yl, benzothiazol (1,3)-2-yl, 6-chloro benzothiazol (1,3)-2-yl, 6-ethoxy benzothiazol (1,3)-2-yl, 3-phenyl-thiadiazole (1,2,4)-5-yl, pyridin-3-yl, quinolin-8-yl, indazol-3-yl, and triazol (1,2,4)-3-yl, wherein the substituents on said phenyl radical are members of the group consisting of halogen, lower alkyl, lower alkoxy, nitro, cyano, carboxy, trifluoromethyl, carboxy lower alkyl, sulphoxy lower alkyl, carbonamide, lower alkyl carbonamide, dilower alkyl carbonamide, sulfonamide, lower alkyl sulfonamide, and dilower alkyl sulfonamide;
- X stands for an anion;
- and wherein the alkyl groups contain from 1-4 carbon atoms;
- said dyestuff being free of sulphonic acid groups.
Dependencies are inferred from the claim text.