Continuous process for scrubbing out hydrogen sulfide and ammonia from coke oven gas
AssigneeFirma Carl Still GmbH & Co. KG
InventorsHeinrich Weber, Gustav Choulat, Dieter Laufhutte
Life of this patent
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Abstract
A continuous process is provided for scrubbing hydrogen sulfide and ammonia from coke oven gases by selectively scrubbing the hydrogen sulfide using aqueous ammonia, then distilling the hydrogen sulfide again from the wash liquor combining the ammonia directly with acids or certain acid salts, e.g., sulfuric acid or ammonium bisulfate, liberating the combined ammonia therefrom by decomposition, and then recycling the released ammonia to the hydrogen sulfide scrubber, thereby increasing the ratio of ammonia to hydrogen sulfide therein. A preferred absorbent for ammonia is monoammonium phosphate.
Claims9
In a process for removing hydrogen sulfide and ammonia from coke-oven gas by scrubbing in a scrubber, wherein the hydrogen sulfide is removed with aqueous ammonia while also using gaseous ammonia, the source of both the aqueous and gaseous ammonia being said coke-oven gas, and wherein the hydrogen sulfide is subsequently separated by distillation from the aqueous ammonia enriched with hydrogen sulfide and thereafter the lean aqueous ammonia recycled to said scrubber, and thereupon, the ammonia in excess contained in the coke-oven gas and not needed for the scrubbing is absorbed by aqueous mono-ammonium phosphate while forming di-ammonium phosphate and ammonia is separated from the ammonia-enriched aqueous ammonium phosphate by distillation, after a preliminary degassing and formation of ammonia-containing degassing gases as well as recovery of mono-ammonium phosphate, and processed to pure ammonia, the improvement wherein ammonia-containing degassing gases are introduced into said scrubber and said gases are used as gaseous ammonia in the scrubbing of hydrogen sulfide from the coke-oven gas, the ammonia in excess contained in the coke-oven gas is partly scrubbed out along with the hydrogen sulfide and conducted, together with the hydrogen sulfide, into a deacidifier for being distilled, and the rest of the ammonia is scrubbed out with aqueous mono-ammonium phosphate whereupon the aqueous ammonium phosphate strips the ammonia from the coke-oven gas and distillation vapors in scrubbers arranged in series, and the degassing gases contain 5 to 10% by weight of ammonia, a total of 2% by weight of hydrogen sulfide, carbon dioxide, hydrogen cyanide, carbon monoxide and hydrogen, as well as 88 to 93% by weight of water vapor.
In a continuous process for removal of hydrogen sulfide and ammonia from coke oven gases including:
- in a first step, scrubbing said coke oven gases to remove the ammonia with water and thus produce aqueous ammonia and in a second step, scrubbing the hydrogen sulfide substantially selectively by aqueous ammonia, or a mixture of aqueous and gaseous ammonia in a hydrogen sulfide scrubber, the improvement which comprises distilling said hydrogen sulfide from the ammoniacal wash waters of the hydrogen sulfide scrubber, the re-cycling the so-regenerated aqueous ammonia from said waters to said second step;
- absorbing the ammonia contained in the coke oven gas with sulfuric acid or a solution or suspension of ammonium bisulfate for absorbing the ammonia from the coke oven gas;
- liberating and recovering substantially pure ammonia therefrom by thermal decomposition;
- and adding the so-liberated substantially pure ammonia to the hydrogen sulfide scrubber and thereby increasing the ratio of ammonia to hydrogen sulfide therein.
Dependencies are inferred from the claim text.