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US 4,008,189 AGranted
Hydrophilic polyurethane foam
AssigneeOlin Corporation
InventorsBruce G. VAN Leuwen, Clifford J. Maxwell
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Abstract
An improvement is disclosed in the preparation of hydrophilic polyurethane foams. The improvement comprises employing, as the polyol reactant used in making the foam, a mixture of selected oxyalkylated polyhydric alcohols. The resulting foam has improved wet strength properties and is particularly useful in cleaning and similar applications.
Claims13
A process for preparing flexible, hydrophilic polyurethane foam from a reaction mixture comprised of an organic polyisocyanate, a foaming agent, a reaction catalyst, and three polyether polyols, namely,
- a. a first polyol having a molecular weight of about 3,000- 5,000 which is the product of sequentially oxyalkylating an aliphatic triol first with ethylene oxide and then with propylene oxide using a molar ratio, ethylene oxide:
- propylene oxide, from about 0.3:1 to about 1.6:1, said first polyol being used in a weight proportion from about 10 to about 50 percent of the combined weights of said three polyols,
- b. a second polyol having a molecular weight of about 2,000-5,000 which is the product of sequentially oxyalkylating an aliphatic diol first with ethylene oxide and then with propylene oxide using a molar ratio, ethylene oxide:propylene oxide, from about 0.3:1 to about 1.4:1, said second polyol being used in a weight proportion of about 20-50 percent of the combined weights of said three polyols, and
- c. a third polyol having a molecular weight of about 2,400-5,000 which is the product of oxyalkylating an aliphatic triol with a random mixture of ethylene oxide and propylene oxide, the content of ethylene oxide in the mixture being about 5-25% by weight, said third polyol being used in a proportion of about 10-50 percent of the combined weights of said three polyols.
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Dependencies are inferred from the claim text.