Coatings of metal phosphates on metals or glass
AssigneeImperial Chemical Industries PLC
InventorsNeville Colebourne, Nicholas Rolfe, Kevin Thomas McAloon
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Abstract
A metal phosphate coating is applied to a glass article. A liquid composition containing at least in part an organic component and a metal compound having a metal with an atomic number of 12, 14, 20-32, 39-50, 56-80, 90 or 92 and an oxyacid of phosphorus is applied to the glass article. The liquid composition is converted to the metal phosphate coating, i.e., by air drying and/or heating, to give a coating of 0.01 to 5 microns thickness and being transparent to visible light but ultra-violet absorbing.
Claims7
A coated glass article comprising a glass substrate and a coating thereon which has a thickness of 0.01 to 5 microns and is transparent to visible light but ultra-violet light absorbing, said coating being identifiable as the dried residue of a liquid coating composition containing an organic component and a solution of a metal phosphate compound wherein the metal of the compound is selected from the group consisting of iron, titanium, a mixture of iron and titanium and a mixture of iron and chromium, and wherein the phosphate of the compound is an oxyacid of phosphorus, or a compound capable of forming such an oxyacid in the solution of the said compound, the oxyacid being an ortho- or meta-acid of the structure (1) ##STR5## where X.sup.1 and X.sup.2 are the same or different and are selected from hydrogen, hydroxyl, halide or which may have the structure (2) to provide pyrophosphoric acid ##STR6##
The coated article of claim 10 in which the oxyacid of phosphorus is orthophosphoric acid.
The coated article of claim 15 in which the atomic ratio of metal-to-phosphorus is in the range 1:0.5 to 1:2.
The coated article of claim 10 in which the glass article is in the form of a film, filament, sheet, tube, bulb or bottle.
Dependencies are inferred from the claim text.