Hydrolysis of haloaromatic compounds
AssigneeThe Dow Chemical Company
InventorsWilliam E. Smith, Edmund H. Sommerfield
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Abstract
The temperature requirements for hydrolysis of a non-phenolic haloaromatic compound by a concentrated aqueous hydroxide solution are lowered by the presence of a phenolic compound.
Claims14
In the process of hydrolyzing a non-phenolic haloaromatic compound selected from the group consisting of halotoluenes, halobiphenyls, and dihalobenzenes of the group consisting of the o-, m-, and p-chloro- and bromotoluenes, the o-, m-, and p-chloro- and bromo-biphenyls, the o-, m-, and p-dichloro- and dibromobenzenes to produce the corresponding hydroxy aromatic compounds wherein the hydrolysis is effected by reaction of the haloaromatic compound with an alkali metal hydroxide, the improvement comprising conducting the reaction at a temperature of about 250- 330.degree. C, in the presence of a phenolic compound, and with a 50- 100% aqueous alkali metal hydroxide solution.
Dependencies are inferred from the claim text.