Heavy metal complexes of azo dyestuffs containing a heterocyclic diazo component and the residue of 5-halogeno-2,3-dihydrozypyridine as coupling component
AssigneeCiba-Geigy Corporation
InventorsGerhard Back, Alfred Fasciati
Life of this patent
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Abstract
Heavy metal complexes can be prepared from azo compounds that contain a heterocyclic diazo component containing a complex-forming group such as hydroxyl, carboxyl, alkoxy or amino, or containing a hetero nitrogen atom able to form a coordinate bond, exemplified by quinolinyl and benzthiazolyl. The coupling component is 5-halogeno-2,3-dihydroxypyridyl where halogen is preferably chloro or bromo. The dyestuffs are useful, inter alia, for dyeing natural and synthetic polyamides such as wool and nylon. The dyeings obtained are uniform, are resistant to acid and alkali, are fast to light and to rubbing and barely change their appearance in artificial light.
Claims5
The 1:1 and 1:2 cobalt, nickel, copper or chromium complex of a compound of the formula ##STR41## wherein X is chloro or bromo, and
- D is pyridinyl, quinolinyl benzthiazolyl, indazolyl, triazolyl, pyrazolyl, benztriazolyl, benzimidazolyl, thiazolyl, pyrazol-5-one-yl, thiadiazolyl, acrindinyl, carbazolyl or benzisothiazolyl, which is unsubstituted or substituted by chloro, bromo, nitro, cyano, lower alkyl, lower alkoxy, lower alkylsulfonyl, sulfo, carboxy, sulfamoyl, N-lower alkyl sulfamoyl, N-lower hydroxyalkyl sulfamoyl, formylamino, acetamido, benzoylamino, phenylsulfonamido, p-tolylsulfonamido, methylsulfonamido, carboxymethyoxyamino, carboethoxyamino, dimethylaminosulfonylamino, carboisopropoxyamino, phenyl, pyridyl, methylthio, ethylthio, phenylthio, cyclohexylthio, phenylsulfonyl, carbomethoxyethyl, phenylazo, napthylazo, sulfophenylazo or a fiber reactive radical selected from the group consisting of chloroacetyl, bromoacetyl, .beta.-chloropropionyl, .beta.-bromopropionyl, .alpha.,.beta.-dichloropropionyl, .alpha.,.beta.-dibromopropionyl, chloromaleyl, .beta.-chloroacrylyl, .beta.-bromoacrylyl, .alpha.-chloroacrylyl, .alpha.-bromoacrylyl, .alpha.,.beta.-dichloroacrylyl, .alpha.,.beta.-dibromoacrylyl, trichloroacrylyl and chlorocrotonyl;
- said fiber-reactive radical bonded via --NH-- or aminosulfophenylazo.
Dependencies are inferred from the claim text.