Resin rich epoxide-mica flexible high voltage insulation
AssigneeWestinghouse Electric Corp.
InventorJames D. B. Smith
Life of this patent
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Abstract
A flexible mica sheet is made by: (A) mixing solid and liquid epoxide resin in a dual solvent system, (B) adding an organo-titanate catalyst, and mixing to form a homogeneous admixture, (C) applying the admixture to a sheet material comprising mica, so that organo-titanate contacts the mica, causing organo-titanate to act as a latent catalyst, and (D) removing solvent, to form a flexible B staged epoxide resin containing an amount of organo-titanate effective to cure the epoxide in the sheet material heating.
Claims8
A method of making a flexible void free mica sheet material comprising the steps of:
- a. mixing solid epoxide resin, liquid epoxide resin, ketone solvent and aromatic hydrocarbon co-solvent selected from the group consisting of benzene and arene solvents and mixtures thereof;
- wherein the weight ratio of solid epoxide:liquid epoxide is from about 60:40 to 95:5;
- the weight ratio of ketone:
- co-solvent is from about 70:30 to 30:70 and the weight ratio of total epoxide:
- total solvent is from about 85:15 to 30:70, and then
- b. mixing the epoxide -- solvent mixture, with an organo-titanate catalyst selected from compounds having the structural formula Ti(OR).sub.4, wherein each R group is independently selected from the group consisting of alkyl groups having 1 to 10 carbon atoms, aryl groups, Cl, Br or N0.sub.2 substituted aryl groups, alkaryl groups with the alkyl constituent having from about 1-10 carbon atoms, Cl, Br or N0.sub.2 substituted alkaryl groups with the alkyl constituent having from about 1-10 carbons, aralkyl groups with the alkyl constituent having about 1-10 carbon atoms, cyclopentane groups, cyclopentene groups, cyclopentadiene groups, cyclohexane groups, cyclohexene groups, and cyclohexadiene groups, to form a homogeneous admixture,
- c. applying the homogeneous catalyzed epoxide-solvent admixture to a sheet material comprising mica, so that organo-titanate contacts mica causing organo-titanate to act as a latent catalyst,
- d. removing solvent from the epoxide-solvent admixture in the sheet material to form a flexible B staged epoxide resin containing organo-titanate as a latent catalyst contacting mica in the sheet material;
- wherein the amount of organo-titanate added is effective to cure the epoxide in the sheet material upon heating.
A method of making a flexible, void free mica sheet material comprising the steps of:
- a. mixing solid epoxide resin, liquid epoxide resin, ketone solvent having from 3 to 6 carbon atoms in the molecule and an aromatic hydrocarbon co-solvent selected from the group consisting of benzene, toluene, ethylbenzene, xylene and mixtures thereof;
- wherein the weight ratio of solid epoxide:
- liquid epoxide is from about 60:40 to 95:5;
- the weight ratio of ketone:
- co-solvent is from about 70:30 to 30:70 and the weight ratio of total epoxide:
- total solvent is from about 85:15 to 30:70, and then
- b. mixing the epoxide-solvent mixture with an organo-titanate catalyst having the structural formula Ti(OR).sub.4, wherein R is selected from alkyl groups having from 1 to 10 carbon atoms, at a temperature up to about 35.degree. C, to form a homogeneous admixture having a viscosity of between about 25 to 200 cp at 25.degree. C, and then
- c. applying the homogeneous catalyzed epoxide-solvent admixture to a sheet material comprising mica, so that organo-titanate contacts mica causing organo-titanate to act as a latent catalyst, and then
- d. removing at least 95 weight % of the solvent from the epoxide-solvent admixture in the sheet material, at a sheet material temperature of up to about 125.degree. C, to form a flexible B staged epoxide resin, containing organo-titanate as a latent catalyst contacting the mica in the sheet material;
- wherein the amount of organo-titanate added is effective to cure the epoxide in the sheet material upon heating at temperatures of at least about 140.degree. C.
Dependencies are inferred from the claim text.