Flame resistant thermosetting resin composition and method for preparing same
AssigneeSumitomo Bakelite Co., Ltd.
InventorAkira Yoshioka
Life of this patent
Estimating the term…
Abstract
A thermosetting resin may be imparted with favorable flame resistance, heat resistance, and curing characteristics by the incorporation of a heat resistant polyphosphoric acid ester or an organic phosphonate compound containing a hydroxymethyl or amide group. Such a resin is suitable particularly as a material for manufacturing those thermosetting molding compounds, laminates, electrical insulating materials such as insulating varnishes, and adhesives which are required to be flame resistant.
Claims33
A flame resistant thermosetting resin molding, laminating electrical insulatory or adhesive composition comprising a reaction product of a thermosetting resin selected from the group consisting of phenolic resins, epoxy resins, these resins modified with one another, and these resins modified with amino resins at and least one compound selected from the group consisting of phosphorus compounds represented by the general formula, ##STR9## wherein R.sub.1 and R.sub.2, which may be the same or different, represent each an alkyl, aryl, alkoxy, or aryloxy group, which has up to 10 carbon atoms and may have one or more hydroxyl substituents;
- R.sub.3 represents an aromatic ring;
- R.sub.4 represents a hydrogen atom or an alkyl or aryl group, both groups having up to 10 carbon atoms;
- and n is an integer from 2 to 30, phosphorus compounds represented by the general formula, ##STR10## wherein R.sub.5 and R.sub.6, which may be the same or different, represent each an alkyl, alkenyl, or aryl group, which has up to 20 carbon atoms and may have one or more halogen atoms, and phosphorus compounds represented by the general formula, ##STR11## wherein R.sub.8 and R.sub.9, which may be the same or different, represent each an alkyl, alkenyl or aryl group, which has up to 20 carbon atoms and may have one or more halogen substituents, R.sub.7 represents an alkylene, alkenylene or arylene group, which has up to 10 carbon atoms and may have one or more halogen substituents and X represents a hydrogen atom or hydroxymethyl group, the ratio of the phosphorus compound to the thermosetting resin being in the range of 0.7 to 6% by weight in terms of phosphorus atom content of the total resin.
A method for manufacturing a flame resistant thermosetting resin composition for molding, laminating, electrical insulating and adhesives, which is characterized by mixing a thermosetting resin selected from the group consisting of phenolic resins, epoxy resins, these resins modified with one another and these resins modified with amino resins, or the reactants used to form such a thermoplastic resins and effecting the reacting thereof, with at least one compound selected from the group consisting of phosphorus compounds represented by the general formula, ##STR12## wherein R.sub.1 and R.sub.2, which may be the same or different, represent each an alkyl, aryl, alkoxy or aryloxy group, which has up to 10 carbon atoms and may have one or more hydroxyl substituents;
- R.sub.3 represents an aromatic ring;
- R.sub.4 represents a hydrogen atom or an alkyl or aryl group, both groups having up to 10 carbon atoms;
- and n is an integer from 2 to 30, phosphorus compounds represented by the general formula, ##STR13## wherein R.sub.5 and R.sub.6, which may be the same or different, represent each an alkyl, alkenyl, or aryl group, which has up to 20 carbon atoms and may have one or more halogen atoms, and phosphorus compounds represented by the general formula, ##STR14## wherein R.sub.8 and R.sub.9, which may be the same or different, represent each an alkyl, alkenyl or aryl group, which has up to 20 carbon atoms and may have one or more halogen substituents, R.sub.7 represents an alkylene, alkenylene or arylene group, which has up to 10 carbon atoms and may have one or more halogen substituents and X represents a hydrogen atom or hydroxymethyl group, the ratio of the phosphorus compound to the thermosetting resin being in the range of 0.7 to 6% by weight in terms of phosphorus atom content of the total resin.
Dependencies are inferred from the claim text.