Process for manufacturing and separating from petroleum cuts aromatic hydrocarbons of high purity
AssigneeInstitut Francais du Petrole, des Carburants et Lubrifiants et Entreprise de Recherches et d'Activities Petrolieres Elf
InventorsBernard Juguin, Georges Cohen, Paul Mikitenko
Life of this patent
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Abstract
Process for producing aromatic hydrocarbons, particularly benzene and/or toluene from a feed charge containing saturated and unsaturated hydrocarbons, by catalytic treatment of said charge with hydrogen, fractionation of the resulting product to separate a fraction containing benzene and/or toluene, extractive distillation of at least one aromatic hydrocarbon in a column, by means of an extraction solvent from which said hydrocarbon is subsequently separated, and recycling to the reaction zone of at least one portion of the products recovered at the top of said extractive distillation column and containing essentially C.sub.6 and C.sub.7 saturated hydrocarbons.
Claims7
A process for producing aromatic hydrocarbons in which a feed charge containing essentially paraffinic and naphthenic hydrocarbons and aromatic hydrocarbons is subjected to a treatment with hydrogen in at least two reaction zones in the presence of a catalyst, the inlet temperature of at least the last reaction zone traversed by the charge being from 570.degree. to 600.degree.C, the pressure from 1 to 60 kg/cm.sup.2, the hourly flow rate by volume being from 0.1 to 10 times the catalyst volume and the molar ratio of the hydrogen to the hydrocarbons being from about 0.5 to 20, in which process the obtained products are made free from normally gaseous products and then subjected to at least one conventional fractionation so as to obtain a fraction containing essentially hydrocarbons having 4 and 5 carbon atoms per molecule, fractions or mixtures of fractions containing essentially at least one aromatic hydrocarbon selected from toluene, ethyl-benzene and xylenes, and aromatic hydrocarbons containing at least 9 carbon atoms per molecule, and a cut containing essentially, in addition to saturated hydrocarbons consisting essentially of 6 and/or 7 carbon atoms per molecule, a fraction selected from the benzene, toluene and benzene-toluene fractions, said process further comprising subjecting, in an extractive distillation zone, said cut to an extractive distillation in the presence of a suitable extraction solvent, recovering at the bottom of the extractive distillation column a mixture of the extraction solvent and at least one aromatic hydrocarbon, separating said aromatic hydrocarbon from the extraction solvent and recovering, at the top of the extractive distillation zone, a new cut containing non-aromatic products, said process further comprises subjecting said new cut containing the non-aromatic hydrocarbons consisting essentially of saturated hydrocarbons having 6 and/or 7 carbon atoms per molecule to a condensation, removing therefrom at least the major part of the extraction solvent contained therein and recycling at least one portion of the so-purified cut containing the said non-aromatic hydrocarbons towards the last one of the reaction zones, wherein the inlet temperature is comprised between 570.degree. and 600.degree.C, the catalyst of at least said reaction zone, to which said so-purified cut is recycled, containing at least two metals from group VI B, VII B or VIII of the periodic classification of elements, the concentration of each metal being comprised between 0.01 and 5% by weight.
Dependencies are inferred from the claim text.