Method for bonding polyamides to rubber, adhesive for the same, and adhesive coated polyamide reinforcing elements
AssigneeThe General Tire & Rubber Company
InventorsGerard E. van Gils, Edward F. Kalafus
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AssigneeThe General Tire & Rubber Company
InventorsGerard E. van Gils, Edward F. Kalafus
Estimating the term…
An aqueous alkaline dispersion of a rubbery vinyl pyridine copolymer, trimethylol phenol, and a resorcinol compound, in certain amounts is useful in forming an adhesive for bonding polyamide or nylon cords to rubber compounds or stocks. After dipping the cord in the adhesive dip, the coated cord is heated to dry it and heat cure or heat set the adhesive on the cord. Thereafter, the adhesive containing cord is combined or laminated (calendered) with a curable rubber compound and the resulting assembly is cured. High H-adhesions are obtained with this one-step or single treatment coating dip. It is particularly useful for bonding crystalline polyamides having a large number of aromatic groups in the polymeric structure, e.g., "Fiber B."
A composition of matter useful in adhering a polyamide reinforcing element to a rubber compound comprising essentially an aqueous alkaline dispersion of 100 parts by weight of a rubbery vinyl pyridine copolymer, from about 2 to 28 parts by weight of trimethylol phenol, from about 0.5 to 24 parts by weight of at least one water soluble, thermoplastic and non heat hardenable resorcinol compound selected from the group consisting of resorcinol and a resorcinol-formaldehyde novolak, from about 0 to 3 parts by weight of alkaline material selected from the group consisting of NH.sub.3 and NaOH, and from about 170 to 1100 parts by weight of water.
Dependencies are inferred from the claim text.