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US 3,991,014 AGranted
Polyesters of derivatives of hydroquinone and bis(carboxyphenyl)ether
AssigneeE. I. Du Pont de Nemours and Company
InventorJacob John Kleinschuster
Life of this patent
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Abstract
This invention relates to a class of novel polyesters derived from derivatives of hydroquinone and bis(carboxyphenyl)ether and to the fibers and other shaped articles prepared therefrom. Also comprehended by this invention are the novel, optically anisotropic polyester melts from which these shaped articles can be prepared.
Claims12
A fiber-forming melt spinnable polyester capable of forming an anisotropic melt and consisting essentially of units of the formula:
- I --O--A--O--
- and ##SPC2##
- wherein A is selected from the group of chloro-, bromo-, methyl- and dimethyl-1,4-phenylene radicals;
- up to 20 mol % of formula I units may be replaced with --O--X--O-- units where X is selected from the group of 1,4-phenylene, ethyl-, tertiary butyl- and dichloro-1,4-phenylene, 4,4'-biphenylene, oxybis(1,4-phenylene), thiobis(1,4-phenylene), 3,3',5,5'-tetrachloro-4,4'-biphenylene and 3,3',5,5'-tetramethyl-4,4'-biphenylene and up to 20 mol % of formula II units may be replaced with ##EQU4## units where Y is selected from the group of 1,3-phenylene, 1,4-phenylene, chloro-, bromo-, and methyl-1,4-phenylene, 1,4-cyclohexylene, 2,6-naphthylene, 4,4'-biphenylene, and ethylenedioxybis(1,4-phenylene) with the proviso that no more than 10 mol % of the total of formula I, formula II, --O--X--O-- and ##EQU5## units are replaced.
1 more element
Dependencies are inferred from the claim text.