Electrolyte regeneration in a fuel cell stack
AssigneeUnited Technologies Corporation
InventorMurray Katz
Life of this patent
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Abstract
In a fuel cell stack utilizing an alkali metal electrolyte, the electrolyte is distributed in parallel between the electrodes of a plurality of fuel cells and is then fed to regenerator cell which converts carbonate ions to molecular CO.sub.2 gas which is discharged from the cell. Regeneration is effected through the establishment of a hydroxyl ion gradient within a regenerator cell. The regenerated electrolyte is then returned to the fuel cells. In this manner a carbonate buildup in the cells is prevented.
Claims9
In the operation of fuel cell apparatus including a plurality of fuel cells electrically connected in series to each other and to a load, each of said cells comprising a fuel electrode and an oxidant electrode spaced apart and utilizing an alkali metal hydroxide as the electrolyte, a hydrogen containing gas as the fuel, and unscrubbed air directly in the fuel cell electrodes as the oxidant, each electrode including a catalyst-electrolyte interface therein, wherein detrimental carbonate ions are formed in the electrolyte by reaction of the electrolyte with the carbon dioxide present in the air, the process comprising the steps of:
- providing a regenerator cell connected electrically in series with said fuel cells and responsive to the power demand of the load, the regenerator cell comprising a cathode electrode and an anode electrode spaced apart;
- circulating the electrolyte in a single pass through the fuel cells and into contact with both the fuel and oxidant electrodes of said cells during said pass and then between said electrodes of the regenerator cell, wherein the step of circulating the electrolyte through the fuel cells includes the step of distributing said electrolyte in parallel to each of the fuel cells between the electrodes thereof;
- flowing unscrubbed air past and in contact with the nonelectrolyte side of said regenerator cell cathode electrode;
- establishing and maintaining a hydroxyl ion gradient in the regenerator cell between the regenerator cell electrodes, the hydroxyl ion concentration in the electrolyte at the anode electrode being sufficiently low to effect the release of gaseous carbon dioxide from the electrolyte at a steady state rate essentially equivalent to its rate of absorption in the electrolyte in the fuel cells as a function of the power demand of the load;
- and
- venting the carbon dioxide from the stack.
A fuel cell apparatus comprising a plurality of cells electrically connected in series to form a cell stack, each of the cells of said cell stack including a pair of spaced apart electrodes one being an anode electrode and the other being a cathode electrode and each having a catalyst-electrolyte interface therein, the cells of said cell stack being divided into two groups, means providing alkali metal hydroxide electrolyte circulation from one group to the other, the first of said groups consisting of a plurality of fuel cells, said apparatus including means to distribute said electrolyte in parallel between each pair of electrodes of said first group in a single pass, said first group of cells having hydrogen containing gas passing on the nonelectrolyte side of each anode electrode and unscrubbed air passing on the nonelectrolyte side of each cathode electrode, the second group of said cells consisting of one or more regenerator cells, means for flowing said circulating electrolyte between the regenerator cell electrodes and means for flowing unscrubbed air past and in contact with the nonelectrolyte side of said regenerator cell cathode electrode, each regenerator cell including a diffusion barrier disposed adjacent the electrolyte side of said anode electrode thereof for maintaining a hydroxyl ion gradient in said regenerator cell between said anode electrode and said cathode electrode wherein gaseous carbon dioxide is released from the electrolyte at the anode electrode thereof, wherein only the cells of said second group of cells include a diffusion barrier, and means for venting said carbon dioxide released from the electrolyte from said fuel cell apparatus.
Dependencies are inferred from the claim text.