Process for coloring fibrous structures
AssigneeKanebo, Ltd.
InventorsKenji Segoshi, Toshio Kidogami, Chinzo Yamaba
Life of this patent
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Abstract
A process for coloring a fibrous structure which comprises applying a coloring agent and a prepolymer or precondensate of a synthetic resin to a fibrous structure, heat-treating the fibrous structure, and then treating the fibrous structure with a reducing agent.
Claims19
A process for coloring a fibrous structure consisting essentially of fibers selected from the group of natural fibers, semi-synthetic fibers and synthetic fibers which comprises applying a solution of a coloring agent and a methylol compound derived from formaldehyde, the amount of said methylol compound being about 0.7 to 30% by weight of said solution and being about 1 to 20 times the weight of the coloring agent, to the fibrous structure, heat-treating the fibrous structure at 100.degree. to 220.degree. C for 0.1 to 10 minutes and then treating the fibrous structure with a reducing agent selected from the group consisting of hydrogen, hydrogen iodide, hydrogen sulfide, lithium aluminum hydride, sodium borohydride, carbon monoxide, sulfur dioxide, thiourea dioxide, thiourea sulfite, sodium sulfide, polysodium sulfide, ammonium sulfide, alkali metals, magnesium, calcium, aluminum, zinc, iron (II) salts, tin (II) salts, titanium (III) salts, chromium (II) salts, aldehydes, saccharides, sodium bisulfite, Na-sulfoxylate formaldehyde, modified primary zinc salts of formaldehyde sulfoxylic acid and a hydrosulfite said reducing agents being used in an amount of 0.05 to 5% by weight based on the weight of the fibrous structure.
A process for coloring a fibrous structure comprising a blend of polyethylene terephthalate fibers and fibers selected from the group consisting of cotton, viscose and flax which comprises applying (1) a coloring agent comprising a mixture of a disperse dye and a reactive or acid dye and (2) a hydroxyalkyleneurea-formaldehyde precondensate to said fibrous structure in a single bath, said precondensate being employed in an amount of about 0.7 to 30% by weight of said bath and being about 1 to 20 times the weight of said coloring agent;
- heat-treating said fibrous structure at a temperature of from about 130.degree. to 210.degree. C for a period of from about 0.3 to 5 minutes and treating the thus dyed fibrous structure at an alkaline pH with a reducing agent selected from the group consisting of hydrosulfite and a formaldehyde-modified sulfoxylate.
Dependencies are inferred from the claim text.