Adducts, containing epoxide groups, based on polyesterdicarboxylic acids
AssigneeCiba-Geigy Corporation
InventorsRolf Schmid, Friedrich Lohse, Willy Fatzer, Hans Batzer
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AssigneeCiba-Geigy Corporation
InventorsRolf Schmid, Friedrich Lohse, Willy Fatzer, Hans Batzer
Estimating the term…
Adducts containing epoxide groups, which have been (so-called) "advanced" with polyesters containing rings are obtained by reacting adducts containing epoxide groups, which have been obtained by reaction of certain long-chain aliphatic polyesters with diepoxide compounds in excess, with polyesterdicarboxylic acids, containing carbocyclic or heterocyclic rings, while heating, 0.3 - 0.5 carboxyl group equivalent of the polyester-dicarboxylic acid containing rings being employed per 1 epoxide equivalent of the adduct containing epoxide groups. Curing of the (so-called) "advanced" adducts containing epoxide groups gives flexible moulded materials which are distinguished, in particular, by high tear propagation resistance.
An epoxide resin composition consisting essentially of advanced adducts containing epoxide groups, and advanced adducts being formed from ( 1) an adduct containing epoxide groups, which has been obtained by reaction of (a) a polyepoxide compound with (b) 0.3-0.5 carboxyl group equivalent, per 1 epoxide equivalent of the polyepoxide compound (a), of a long-chain aliphatic polyesterdicarboxylic acid of the formula I ##EQU1## wherein A denotes a long-chain polyester residue in which unsubstituted or substituted alkylene and/or alkenylene chains alternate with carboxylic acid ester groups and the quotient Z/Q, wherein Z is the number of carbon atoms present in the recurring structural element of the residue A and Q is the number of oxygen bridges present in the recurring structural element of the residue A, must be at least 4 and wherein, furthermore, the total number of carbon atoms present in the residue A is at least 50, and (2) 0.3-0.5 carboxyl group equivalent per 1 epoxide equivalent of the adduct (1) containing epoxide groups, of a polyester-dicarboxylic acid of the formula II ##EQU2## which is different from the polyester of formula I wherein R.sub.1 and R.sub.2 each is a member selected from the group consisting of divalent aliphatic residue, divalent araliphatic residue, divalent cycloaliphatic residue, divalent cycloaliphatic-aliphatic residue, divalent aromatic residue and divalent heterocyclic-aliphatic residue and at least one of the two residues R.sub.1 and R.sub.2 must contain a carbocyclic or heterocyclic ring or a ring system of this type and the recurring structural element of the formula ##EQU3## does not contain more than 3 methylene groups per ring and n denotes a number from 1 to 30.
Dependencies are inferred from the claim text.