Ammunition priming mixtures and method of forming same
AssigneeRemington Arms Company, Inc.
InventorJoseph F. Kenney
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AssigneeRemington Arms Company, Inc.
InventorJoseph F. Kenney
Estimating the term…
Ammunition rim fire priming mixtures are commonly prepared by mixing normal lead styphnate, a sensitizer, such as tetracene, an oxygen donor such as lead nitrate, and a frictionator such as ground glass. This invention relates to such a mixture and to center fire priming mixtures which consist of lead styphnate, tetracene, inorganic fuels and barium nitrate and to a method of forming them and is characterized by the use of lead styphnate which is formed in situ by the reaction of a water wet mixture of styphnic acid and a lead compound such as lead oxide (litharge), lead hydroxide, basic lead carbonate, or lead carbonate. The lead styphnate which results from the practice of this method has been isolated and subjected to X-Ray diffraction analysis confirming that this is a novel form of lead styphnate and is indeed a new compound. Important advantages of this invention are reduced cost, improved safety since it is unnecessary to prepare, precipitate, or separately handle pure or relatively pure lead styphnate and because the wet mixtures are insensitive, and improved percussion sensitivity of the resulting mixtures when dried for use.
The method of making a new form of normal lead styphnate which consists of reacting styphnic acid free from the impurities usually present in commercial styphnic acid in the presence of water with a non-explosive compound of lead selected from the group of lead compounds consisting of lead oxide, basic lead carbonate, lead carbonate, and lead hydroxide to produce a workable, granular, wet mass of the new form of normal lead styphnate and no by products of the reaction except water or water and carbon dioxide, said new form of normal lead styphnate in the wet state being insensitive to heat, shock, friction, or electrostatic discharge.
A new form of normal lead styphnate characterized by crystalline lattice dimensions which produce Bragg diffractions with relative intensities substantially as tabulated herein:
A new form of normal lead styphnate characterized by a tetragonal unit cell structure of dimensions substantially as follows:
Dependencies are inferred from the claim text.