Novel polyetherimides
AssigneeGeneral Electric Company
InventorsFrank J. Williams, III, Paul E. Donahue
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Abstract
This invention is concerned with a new class of polyetherimides. More particularly, the invention is concerned with polyetherimides derived from the reaction of an organic diamine, a bisphenol dianhydride and a dianhydride selected from the class consisting of pyromellitic dianhydride, a sulfur dianhydride, and a benzophenone dianhydride. The polyetherimide compositions have improved solvent resistance which enhances their value in a wide variety of uses including films, molding compounds, coatings, etc.
Claims12
A polyetherimide of the formula
- [A].sub.m [B].sub.1.sub.-m,
- where the m is a number greater than 0 and smaller than 1, where A units are of the formula:
- ##SPC20##
- where --O--Z--O-- is in the 3 or 3'- and 4 or 4'-positions and Z is a member of the class consisting of (1) ##SPC21##
- and (2) divalent organic radicals of the general formula:
- ##SPC22##
- where X is a member selected from the class consisting of divalent radicals of the formulas, --C.sub.y H.sub.2y --, ##EQU1## --O-- and --S--, where q is 0 or 1, y is a whole number from 1 to 5, R is a divalent organic radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (b) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, C.sub.(2.sub.-8) alkylene terminated polydiorganosiloxane, and (c) divalent radicals included by the formula ##SPC23##
- where Q is a member selected from the class consisting of --O--, ##EQU2## --S--, and --C.sub.x H.sub.2x --, and x is a whole number from 1 to 5 inclusive, and where the B units are of the formulas:
- ##SPC24##
- or mixtures thereof, where R is a divalent organic radical as previously defined, and independently a and b represent a whole number in excess of 1.
A polyetherimide of the formula [A].sub.m [B].sub.1.sub.-m, where m is a number greater than 0.75, where the A units are of the formula:
- ##SPC28##
- and where the units are of the formulas:
- ##SPC29##
- or mixtures thereof, where R is a divalent organic radical as previously defined, and independently a and b represent a whole number in excess of 1.
A polyetherimide of the formula [A].sub.m [B].sub.1.sub.-m where A is the formula:
- ##SPC34##
- and B is the formula:
- ##SPC35##
Dependencies are inferred from the claim text.