Method for sealing breaches in multi-layer ultrathin membrane composites
AssigneeGeneral Electric Company
InventorWarella R. Browall
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Abstract
A method is described for sealing pinholes and covering imperfections passing through a multi-layer membrane composite to be employed for conducting a gas separation process. The particular breaches through such composites that this invention is intended to deal with are those caused by the unavoidable presence of particles smaller than about 3000 A. By this method an additional ultrathin membrane of very flexible, permeable polymer material is applied over the outer surface of the membrane composite.
Claims7
In the method of preparing ultrathin membrane structures intended for use in the separation of a specific gas from a gas mixture wherein at least one ultrathin membrane layer for accomplishing said gas separation is applied over a smooth microporous substrate to form a basic ultrathin membrane composite and breaches through said at least one layer are patched, the improvement comprising the steps of:
- a. casting a non-porous ultrathin film from a sealing material of high flexibility exhibiting at least about 3.5 times the permeability to said specific gas as the material of said at least one layer, being less selective to said specific gas than the material of said at least one layer and being directly bondable to said at least one layer and
- b. applying said non-porous film of sealing material over said composite covering the outer surface of said at least one layer
- whereby the need for patching is greatly reduced.
A composite consisting of ultrathin polymer layers supported on a microporous backing layer, said polymer layers forming a unified non-porous laminate of a polyphenylene oxide/organopolysiloxane-polycarbonate copolymer layer disposed between and bonded to layers of organopolysiloxane-polycarbonate.
Dependencies are inferred from the claim text.