A process for the manufacture of artificial leather and for imparting a napped, or nubuck grain finish thereto comprising the steps of providing a backing member comprising a matrix of crossing strands of fibers, contacting at least one side of said backing member with a polymeric system comprising a mixture of a heat-reactive latex and a carboxylated latex, the latter being self-cross-linkable at a more rapid rate than the former under application of heat, at a temperature in a range of about 60.degree.C. to about 135.degree.C., subjecting said contacted backing member to a temperature within said range for a period of time to effect sequential cross-linking of said carboxylated latex about the points of crossing of said strands and of said heat-reactive latex about said cross-linked carboxylated latex and drying of the contacted backing member, and thereafter buffing said one side in two steps, the direction of the second buffing step being shifted an angle of 180.degree. from the first buffing step thereby mechanically altering said one side of the dried backing member to provide an irregular leather-like surface thereto consisting of elongated fibers from said backing member and shorter villi of said cross-linked, heat-reactive latex.