Process for drawing acrylic fibrous materials to form a product which particularly is suited for thermal stabilization and carbonization

In a continuous process for the drawing of an acrylic multifilament fibrous material selected from the group consisting of an acrylonitrile homopolymer and an acrylonitrile copolymer containing at least about 85 mol percent of acrylonitrile units and up to about 15 mol percent of one or more monovinyl units copolymerized therewith wherein a continuous length of said multifilament fibrous material is continuously passed for a brief residence time through a drawing zone provided at a temperature of about 100.degree. to 175.degree.C. while under the influence of a longitudinal tension wherein said continuous length of multifilament fibrous material is elongated while undergoing no substantial thermal stabilization;

• the improvement comprising:
• a. passing said continuous length of acrylic fibrous material prior to said drawing through a liquid medium containing a dispersion of powdered graphite so as to coat the surface of the individual filaments of said fibrous material with said liquid medium, and
• b. passing said resulting continuous length of acrylic multifilament fibrous material bearing said coating of said liquid medium thereon through a drying zone wherein the liquid portion of said medium is substantially expelled and the surface of the filaments is provided with a coating of said powdered graphite wherein an uptake of powdered graphite of about 0.5 20 percent by weight based upon the weight of the fibrous material is accomplished with said powdered graphite serving to improve the drawing properties of said acrylic multifilament fibrous material and aiding in the formation of an elongated multifilament fibrous material which is particularly suited for thermal stabilization and carbonization to form a multifilament carbonaceous fibrous material.