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US 3,975,379 AGranted
Dihydroindoles and indolenine dyestuffs
AssigneeBayer Aktiengesellschaft
InventorErnst Schmitt
Life of this patent
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Abstract
Dihydroindoles of the formula ##SPC1## And their use as coupling or condensation components for the manufacture of basic indolenine dyestuffs of the formula ##SPC2## The dyestuffs are used for dyeing and printing natural are used for dyeing and printing natural and synthetic materials.
Claims7
Methine dyestuff of the formula ##SPC37##
- in which
- R.sub.1 and R.sub.2 are C.sub.1 --C.sub.4 -alkyl;
- R.sub.3 is hydrogen, a non-ionic substituent, carboxyl, or together with the ring, to which it is attached, a benzene ring;
- n is 1, 2, 3 or 4;
- R.sub.4 and R.sub.5 are hydrogen or a non-ionic substituent;
- X.sup.(.sup.-) is an anion;
- said non-ionic substituents selected from the group consisting of C.sub.1 --C.sub.9 alkyl, chloromethyl, C.sub.1 --C.sub.12 -alkoxymethyl, phenoxymethyl, p-nitrophenoxymethyl, p-methoxyphenoxy, p-chlorophenoxymethyl, allyloxymethyl, propargyloxymethyl, hydroxymethyl, di-C.sub.1 --C.sub.4 -alkylaminomethyl, diallylaminomethyl, pyrrolidinomethyl, phthalimidomethyl, allyl, trifluoromethyl, phenyl, benzyl, cyclohexyl, C.sub.1 --C.sub.4 -alkoxy, sulfamoyl, CN, carbomethoxy, carboethoxy, fluorine, chlorine, methylmercapto, methylsulfonyl and acetylamino;
- B.sub.1 is CH -- Ar.sub.1 or ##EQU8## Z together with C and N to which it is attached, forms an indolinyl-2-ring;
- Ar.sub.1 is a radical of the p-amino-benzene, naphthalene;
- benzofurane, benzothiophene, indole, indoline, 1,2,3,4-tetrahydroquinoline, carbazole, quinoxaline, dihydro-[benzo-1,4-oxazine], dihydro-[benzo-1,4-thiazine], 9, 10-dihydro-phenazine, phenoxazine or phenthiazine series;
- R.sub.6 is methyl, ethyl or benzyl.
8 more elements
Dependencies are inferred from the claim text.