Water-insoluble reactive dyestuffs which are soluble in aprotic solvents
AssigneeCiba-Geigy Corporation
InventorsHerbert Seiler, Paul Dussy
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AssigneeCiba-Geigy Corporation
InventorsHerbert Seiler, Paul Dussy
Estimating the term…
Valuable reactive dyestuffs containing no acid, salt-forming, water-solubilizing groups and which, among others, can be applied from organic solvents, especially aprotic solvents correspond to the formula ##EQU1## wherein D represents the radical of an organic dyestuff, Q represents the bridging member --NX.sub.3 --, --O--, --S-- or --NX.sub.3 CO--, whereby X.sub.3 denotes hydrogen or a lower alkyl group, R represents the radical of a nitrogen heterocycle containing at least one substituent which can be split off as anion and which is bound to a ring carbon atom adjacent to a tertiary nitrogen atom, X.sub.1 represents hydrogen, an alkyl or an alkoxyalkyl group and X.sub.2 represents an alkyl or an alkoxyalkyl group having in all at least 4 carbon atoms, whereby X.sub.1 and X.sub.2 must together contain, when X.sub.1 denotes an alkyl or an alkoxyalkyl group, at least 8 carbon atoms, Or X.sub.1 represents a cyclohexyl radical, unsubstituted or substituted by lower alkyl groups having preferably 1 to 4 carbon atoms, and X.sub.2 represents an unsubstituted or substituted alkyl group having at most 18 carbon atoms, a lower alkenyl group having preferably 1 to 4 carbon atoms or a cyclohexyl radical, unsubstituted or substituted by lower alkyl groups having preferably 1 to 4 carbon atoms. Fiber materials dyed with these dyestuffs exhibit very good fastness properties, especially fastness to wet processing, rubbing and dry-cleaning.
A reactive dyestuff, containing no acid, salt-forming, water-solubilizing groups, of the formula ##EQU5## wherein D represents the radical of an anthraquinone dyestuff, which is unsubstituted or substituted only by halogen, cyano, nitro, lower alkyl, lower alkenyl, perfluoro(lower)alkyl, hydroxy(lowr) alkyl, cyanoethyl, .beta.,.beta.-dicyanovinyl, lower alkoxy, phenoxy, methylphenoxy, lower alkylthio, phenylthio, lower alkanoyl, lower alkylsulphonyl, phenylsulfonyloxy, dimethylamino, amino, N-(.beta.-cyanoethyl)-ethylamino, diethylamino, methylethylamino, ethylbenzylamino, ethylbutylamino, N-(.beta.-hydroxyethyl)ethylamino, .beta.-hydroxyethylamino, di(.beta.-hydroxyethyl)amino, N-(.beta.-cyanoethyl)-.beta. -hydroxyethylamino, di(.beta.-cyanoethyl)amino, anilino, oxyanilino, methylamino, dimethylanilino, methylanilino, lower alkanoylamide, lower alkoxycarbonylamide, benzoylamide, lower alkylsulphonylamide, N-lower-alkyl- and N,N-diloweralkyl-lower alkylsulphonylamide or hydroxy,
Dependencies are inferred from the claim text.