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US 3,971,740 AGranted
Monoazo compounds
AssigneeCiba-Geigy Corporation
InventorsNalin Binduprasad Desai, Ponnusami Jayaraman, Visvanathan Ramanathan, Klaus Artz, Navnitrai Nagarji Naik, Walter Jenny
Life of this patent
Estimating the term…
Abstract
Azo dyestuffs containing at least one group of formula --X--CO--NR--SO.sub.2 aryl, wherein R is hydrogen alkyl or cycloalkyl and X is an oxygen or sulphur atom or a group of formula --NR.sub.1 --, wherein R.sub.1 is hydrogen alkyl or cycloalkyl. The dyestuffs dye polyester fibers in fast shades.
Claims3
A dyestuff of the formula ##SPC62##
- wherein
- D is selected from the group consisting of thiazole-(2)-, 5-nitrothiazole-(2)-, 5-methylsulphonylthiazole-(2)-, 5-cyanothiazole-(2)-, 4-methyl-5-nitrothiazole-(2)-, 4-methylthiazole-(2)-, 4-phenylthiazole-(2)-, 4-(4'-chloro)- phenylthiazole-(2)-, 4-(4'-nitro)- phenylthiazole-(2)-, pyridine-(3)-, quinoline-(3)-, pyrazole-(3)-, 1-phenylpyrazole-(3)-, indazole-(3)-, 1,2,4-thiazole-(3)-, 5-(methyl, ethyl, phenyl or benzyl)-1,2,4-triazole-(3)-, 1-(4'-methoxyphenyl)-pyrazole-(3)-, benzthiazole-(2)-, 6-methylbenzthiazole-(2)-, 6-methoxybenzthiazole-(2)-, 6-chlorobenzthiazole-(2)-, 6-cyanobenzthiazole-(2)-, 6-thiocyanatobenzthiazole-(2)-, 6-nitrobenzthiazole-(2)-, 6-carbethoxybenzthiazole-(2)-, 4- or 6-methylsulphonylbenzthiazole-(2)-, 1,3,4-thiadiazole-(2)-, 1,3,5-thiadiazole-(2)-, 4-(phenyl or methyl)-1,3,5-thiadiazole-(2)-, 5-phenyl-1,3,4-thiadiazole-(2)-, 3-nitro-5-methylsulphothiophene-(2)-, 3,5-bis(methylsulpho)-thiophene-(2)-, 3-methylisothiazole-(5)-, 4-cyanopyrazole-(2)-, 2-(4'-nitrophenyl)-4-cyanopyrazole-(3)-, phthalimide-(3)-, or ##SPC63##
- R.sub.1 ' and R.sub.2 ' are each hydrogen, alkyl of 1 to 4 carbon atoms, benzyl, .beta.-phenylethyl;
- .beta.-chloroethyl, .beta.,.beta.,.beta.-trifluoroethyl, .beta.,.gamma.-dichloropropyl, .beta.-cyanoethyl, .beta.-ethoxyethyl, .delta.-methoxybutyl, .beta.-hydroxyethyl, .beta.,.gamma.-dihydroxypropyl, .beta.-nitroethyl, (.beta.-carbomethoxy)-ethyl, (.beta.-carboethoxy)-ethyl, (.beta.-carbopropoxy)-ethyl, (.beta.-carbomethoxy)-propyl, (.gamma.-carbomethoxy)-propyl, (.beta.-carboethoxy)-propyl, (.gamma.-carboethoxy)-propyl, (.beta.-acetyl)-aminoethyl, (.beta.-formyl)-aminoethyl, .beta.-acetoxyethyl, .beta.,.gamma.-diacetoxypropyl, .beta.-methanesulfonylethyl, .beta.-ethanesulfonylethyl, .beta.-(p-chlorobenzenesulfonyl)-ethyl, .beta.-methylcarbamyloxyethyl, .beta.-phenyl-carbamyloxyethyl, (.beta.-methoxy)-carbonyloxyethyl, (.beta.-ethoxy)-carbonyloxyethyl, (.beta.-isopropoxy)-carbonyloxyethyl, .gamma.-acetamidopropyl, .beta.-(p-nitrophenoxy)-ethyl, .beta.-(p-hydroxyphenoxy)-ethyl, .beta.-(.beta.'-acetylethoxycarbonyl)-ethyl, .beta.-[(.beta.'-cyano)ethoxycarbonyl]-ethyl, .beta.-[(.beta.'-hydroxy) ethoxycarbonyl]-ethyl, .beta.-[(.beta.'-methoxy)ethoxycarbonyl]-ethyl, .beta.-carboxyethyl, .beta.-acetylethyl, .gamma.-aminopropyl, .beta.-diethylaminoethyl, or .beta.-cyanoacetoxyethyl,
- d is hydrogen, methyl, ethyl, methoxy, ethoxy, phenylthio or phenoxy,
- c is hydrogen, methyl, ethyl, methoxy, ethoxy, phenylthio, phenoxy, chloro, bromo, CF.sub.3 --, methylsulfonyl, methylsulfonylamino, ethanesulfonylamino, p-toluenesulfonylamino, phenoxycarbonylamino, methoxycarbonylamino, or aminocarbonylamino, and in which one or two of c, d, R.sub.1 ', or R.sub.2 ' is substituted by a group of the formula
- --X--CO--N(R)--SO.sub.2 --R.sub.2
- wherein
- R.sub.2 is alkyl of 1 to 4 carbon atoms, cyclohexyl, p-tolyl, 2,5-dimethylphenyl, phenyl, 4-chloro, bromo or fluorophenyl,
- X is --O--, --S-- or --NR--, and
- R is hydrogen, alkyl of 1 to 3 carbon atoms, or cyclohexyl.
8 more elements
Dependencies are inferred from the claim text.