Extremely low viscosity adducts of lactams with alcohols
AssigneeBayer Aktiengesellschaft
InventorKuno Wagner
Life of this patent
Estimating the term…
Abstract
Adducts useful as solvents are prepared from lactams and an aliphatic, cycloaliphatic or araliphatic alcohol or thioalcohol. Solutions of the adducts in the lactam, alcohol or thioalcohol are also disclosed as well as a process for preparing the adducts and solutions thereof.
Claims8
Adduct of a lactam selected from the group of epsilon-caprolactam, 1-N-methyl hexahydro-1,4-diazepin-3-one, propiolactam, butyrolactam, valerolactam and dodecalactam, with an alcohol selected from the group of methanol, ethanol, propanol, n-butanol, isopropanol, t-butanol, cyclohexanol, allyl alcohol, ethylene glycol monomethyl ether, benzyl alcohol, chloroethanol, fluoroethanol, trichloroethanol, trifluoroethanol, beta-hydroxypropylester of C.sub.1-4 carboxylic acids, furfuryl alcohol, tetrahydrofurfuryl alcohol, n-butyl mercaptan, dodecyl mercaptan, mercaptoethanol, a hemiacetal of the foregoing alcohols with formaldehyde or chloral;
- ethylene glycol;
- diethylene glycol;
- thioglycol;
- a propane diol isomer;
- di- or tri-propylene glycol;
- glycerine, tri-methylol propane, hexane-1,6-diol or other isomer of hexane diol;
- hexahydroquinone;
- 1,4-bis-hydroxymethyl cyclohexane;
- terpin hydrate;
- mono-, di, tri- or tetra-methylol cyclohexanone;
- anhydroenneaheptiotol;
- phthalic or terephthalic acid diglycol ester;
- methylene glycol;
- a mono- or bis-hemiacetal of formaldehyde or chloral of any of the aforementioned polyhydroxyl compounds;
- n-methyl diethanolamine;
- bis hydroxyethyl cyclo-hexylamine;
- and bis-hydroxyethyl stearylamine, and an N-methylol derivative of valeorlactam, butyrolactam, caprolactam, propiolactam, N-butylethylurethan, N-methylol benzamide, N-hydroxymethyl naphthalimide, ethanolamine, N-methylethanol amine, cyclohexylethanolamine, oxethylated benzoic acid amide, hydroxyethyl acetamide, hydroxyethyl carbamic acid butyl ester, N,N-dimethylethanolamine, N,N-diethylethanolamine, and hydroazinoethanol, said adduct containing from 0.3 to 4 moles of said alcohol per mol of said lactam.
Adduct of a lactam selected from the group of epsilon-caprolactam, 1-N-methyl hexahydro-1,4-diazepin-3-one, propiolactam, butyrolactam, valerolactam and dodecalactam, with primary and secondary alcohols containing cyclic acetal group of formaldehyde, acetaldehyde or acrolein and alcohols with carbonyl or oxirane groups in the molecule, said adduct containing from 0.3 to 4 moles of said alcohol per mol of said lactam.
Dependencies are inferred from the claim text.