Color photographic silver halide light-sensitive materials
AssigneeFuji Photo Film Co., Ltd.
InventorsYasushi Oishi, Reiichi Ohi, Yoshio Kosuge
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Abstract
A color photographic silver halide light-sensitive material containing a 2-equivalent alpha-acylacetoamide yellow dye-forming coupler and a monoalkylhydroquinone.
Claims17
A color photographic silver halide light-sensitive material comprising a support having coated thereon at least one hydrophilic colloid silver halide emulsion layer containing a non-diffusible alpha-acylacetoamide dye-forming coupler represented by the forumula (II):
- ##EQU10## wherein Y.sub.1 is an aliphatic group, an aromatic group or a heterocyclic group, Y.sub.2 is an aromatic group or a heterocyclic group and X is a member selected from the group consisting of a fluorine atom, an acyloxy group, an aryloxy group, a heterocyclic oxy group, a cyclic acylamino group or a cyclic acysulfonylamino group,
- said emulsion layer or a hydrophillic colloid layer adjacent thereto containing a monoalkylhydroquinone represented by formula (I) or a compound capable of releasing said monoalkylhydroquinone by hydrolysis in aqueous alkaline solution:
- ##SPC12##
- wherein R.sub.1 is an alkyl group having at least 4 carbon atoms.
A color photographic silver halide light-sensitive material comprising a support having coated thereon a silver halide emulsion layer containing a non-diffusible alpha-acylacetoamide yellow dyeforming coupler represented by the formula (II):
- ##EQU12## wherein Y.sub.1 is an aliphatic group, an aromatic group or a heterocyclic group, Y.sub.2 is an aromatic group or a heterocyclic group, and X is a member selected from the group consisting of a fluorine atom, an acyloxy group, an aryloxy group, a heterocyclic oxy group, a cyclic acylamino group or a cyclic acylsulfonylamino group, and a hydrophilic colloid layer containing tert-octylhydroquinone.
A color photographic silver halide light-sensitive material comprising a support having coated thereon a silver halide emulsion layer containing a non-diffusible alpha-acylacetoamide yellow dye forming coupler represented by the formula (II):
- ##EQU13## wherein Y.sub.1 is an aliphatic group, an aliphatic group, an aromatic group or a heterocyclic group, Y.sub.2 is an aromatic group or a heterocyclic group, and X is a member selected from the group consisting of a fluorine atom, an acyloxy group, an aryloxy group, an heterocyclic oxy group, a cyclic acylamino group or a cyclic acylsulfonylamino group, and containing a monoalkylhydroquinone represented by the formula (I) or a compound capable of releasing said monoalkylhydroquinone by hydrolysis in aqueous alkaline solution:
- ##SPC14##
- wherein R.sub.1 is an alkyl group having at least 4 carbon atoms in said silver halide emulsion layer or a hydrophilic colloid layer.
A color photographic silver halide light-sensitive material comprising a support having coated thereon a silver halide emulsion layer containing a non-diffusible alpha-acylacetoamide yellow dye-forming coupler represented by the formula (II):
- ##EQU14## wherein Y.sub.1 is an aliphatic group, an aromatic group or a heterocyclic group, and X is a member selected from the group consisting of a fluorine atom, an acyloxy group, an aryloxy group, a heterocyclic oxy group, a cyclic acylamino group or a cyclic acylsulfonylamino group, and a hydrophilic colloid layer containing a hydroquinone of which the benzene ring is substituted with one alkyl group having 4 to 10 carbon atoms, or a compound capable of releasing said monoalkylhydroquinone by hydrolysis in aqueous alkaline solution.
A color photographic silver halide light-sensitive material comprising a support having coated thereon a silver halide emulsion layer containing 0.2 to 5.0 millimol/m.sup.2 of a non-diffusible alpha-acylacetoamide yellow dye-forming coupler represented by the formula (II):
- ##EQU15## wherein Y.sub.1 is an aliphatic group, an aromatic group or a heterocyclic group, Y.sub.2 is an aromatic group or a heterocyclic group, and X is a coupling-off group, and containing 0.002 to 0.08 part by weight of a monoalkylhydroquinone represented by the formula (I) or a compound capable of releasing said monoalkylhydroquinone by hydrolysis in aqueous alkaline solution:
- ##SPC15##
- wherein R.sub.1 is an alkyl group having at least 4 carbon atoms in said silver halide emulsion layer or a hydrophilic colloid layer per part by weight of the yellow dye-forming coupler.
A color photographic silver halide light-sensitive material containing a 2-equivalent alpha-acylacetoamide yellow dye-forming coupler of the formula (II):
- ##EQU16## wherein Y.sub.1 is an aliphatic group, an aromatic group or a heterocyclic group, Y.sub.2 is an aromatic group or a heterocyclic group and X is a member selected from the group consisting of a fluorine atom, an acyloxy group, an aryloxy group, a heterocyclic oxy group, a cyclic acylamino group or a cyclic acylsulfonylamino group, and a monoalkylhydroquinone.
A color photographic silver halide light-sensitive material containing a 2-equivalent alpha-acylacetoamide yellow dye forming coupler of the formula (II):
- ##EQU17## wherein Y.sub.1 is an aliphatic group, an aromatic group or a heterocyclic group, Y.sub.2 is an aromatic group or a heterocyclic group and X is a member selected from the group consisting of fluorine, an acyloxy group, an anyloxy group, a heterocyclicthio group, a heterocyclicoxy group, a heterocylicthio group, a cyclic diacylamino group and a cyclic acylsulfonylamino group, and a monoalkylhydroquinone represented by the formula (I) or a compound capable of releasing said monoalkylhydroquinone by hydrolysis in aqueous alkaline solution:
- ##SPC16##
- wherein R.sub.1 is an alkyl group having at least 4 carbon atoms.
Dependencies are inferred from the claim text.