Manufacture of particulate expandable styrene polymers requiring shot minimum residence times in the mold
AssigneeBadische Anilin- & Soda-Fabrik Aktiengesellschaft
InventorsHeinz Burger, Ludwig Zuern, Karl Buchholz, Erhard Stahnecker
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Abstract
Particulate expandable styrene polymers requiring short residence times in the mold are obtained by polymerizing styrene and, optionally, other copolymerizable monomers in the presence of expanding agents and from 0.001 to 0.1% by weight of a brominated oligomer or polymer of a 1,3-diene for at least part of the time at temperatures of from 110.degree. to 140.degree.C.
Claims5
A process for the manufacture of particulate expandable styrene polymers requiring short minimum mold residence times by polymerizing styrene or mixtures of styrene and other copolymerizable monomers in the presence of low-boiling hydrocarbon expanding agents and from 0.001 to 0.1% by weight, based on the monomers, of a brominated oligomer or polymer of a 1,3-diene having a maximum degree of polymerization of 2000 and containing more than 40% by weight of bromine at elevated temperatures, wherein the particles forming during polymerization of styrene or said mixtures in the presence of the bromine compounds are heated, in the course of their manufacture, to temperatures of from 110.degree. to 140.degree.C.
Dependencies are inferred from the claim text.