Lamellar micelle containing compositions which exhibit retro-viscous properties
AssigneeMarathon Oil Company
InventorsKarl D. Dreher, William B. Gogarty
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AssigneeMarathon Oil Company
InventorsKarl D. Dreher, William B. Gogarty
Estimating the term…
Compositions containing lamellar micelles and which exhibit retro-viscous property at noncryogenic temperatures are prepared by mixing 4-15 percent of a surfactant (preferably an alkaryl sulfonate having an average equivalent weight of 350-525), 30-70 percent of a liquid hydrocarbon, 15-66 percent of water and optionally up to 20 percent of a cosurfactant, preferably an alcohol containing 1-20 carbon atoms, and/or electrolyte (preferably inorganic salt). The micelles have an axial ratio of at least 3.5 and preferably the composition has a viscosity of at least 75 cp. at a shear rate of 10 sec.sup.- .sup.1 at 23.degree.C. The composition is substantially optically clear, phase stable, birefringent, and the flow properties are such that substantially large increases in flow rate, e.g. 20-fold, can be realized at very small increases in pressure drop, e.g. 5 percent. Uses for the compositions include stimulation of wells (e.g. fracturing fluids), drilling fluids, carrier fluids in pipelines, fluidics, cutting oils, and similar applications.
A composition containing lamellar micelles having an axial ratio of at least 3.5 and which is substantially optically clear, substantially phase stable, exhibits birefringence, and exhibits a substantial increase in flow rate at minor increase in pressure drop while the fluid is under flow conditions at a certain pressure, the composition having a viscosity of at least 75 cps. at a shear rate of 10 sec.sup.-.sup.1 and is comprised of about 30 to about 70% of a liquid hydrocarbon, about 15 to about 66% of water, and about 4 to about 15% of surfactant which is a sulfonate having an average equivalent weight of 350 to about 525, or a carboxylate having an average equivalent weight of about 200 to about 500, the percents based on weight.
A composition containing lamellar miscelles having an axial ratio of at least 3.5 and which composition is substantially optically clear, substantially phase stable, exhibits birefringence, and exhibits a substantial increase in flow rate at minor increase in pressure drop while the fluid is under flow conditions at a certain pressure comprised of about 4 to about 15% of an alkyl aryl sulfonate having an average equivalent weight within the range of about 350 to about 525, about 30 to about 70% of a liquid hydrocarbon, about 15 to about 66% of water, and about 0.01 to about 20% of acosurfactant containing 1 to about 20 carbon atoms.
Dependencies are inferred from the claim text.