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US 3,950,419 AGranted
Aromatic carboxylic acid esters and amides as fixing agents
AssigneeSandoz Ltd., (Sandoz AG)
InventorsHans-Peter Baumann, Hans-Georg Karmann
Life of this patent
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Abstract
The present invention relates to methods of dyeing and printing of textile materials and specifically to the use of fixing agents in such methods. In particular, the present invention relates to the use of aromatic carboxylic acid esters and amides as fixing agents in the dyeing and printing of textile materials.
Claims8
A compound of the formula, ##SPC18##
- wherein Y.sub.1 and Y.sub.2 are, independently, ethylene, 1,2-propylene, 1,3-propylene, 1,2-butylene or phenylethylene, with the proviso that
- a. only the group Y.sub.1 or Y.sub.2 which is bound to X can be 1,3-propylene, and
- b. each (Y.sub.1 -O) or (Y.sub.2 -O) chain contains no more than 2 phenylethylene groups,
- R.sub.4 " is hydrogen, --CO.sub.2 M, --OR.sub.6 or a group --CO--X--(Y.sub.1 O).sub.m.sbsb.1 --R.sub.1,
- R.sub.5 " is hydrogen, --CO.sub.2 M or a group --CO--X--(Y.sub.1 O).sub.m.sbsb.1 --R.sub.1,
- M is a charge equivalent of a cation,
- R.sub.6 is hydrogen, phenyl, phenylalkyl (C.sub.7 -C.sub.22), phenyl or phenylalkyl (C.sub.7 -C.sub.22) substituted by --OH, alkyl or halogen and having up to 22 carbon atoms in the aggregate thereof, alkyl (C.sub.1 -C.sub.22), cycloalkyl (C.sub.5 -C.sub.7), alkyl (C.sub.1 -C.sub.15) cycloalkyl (C.sub.5 -C.sub.7), cycloalkyl (C.sub.5 -C.sub.7) alkyl (C.sub.1 -C.sub.15) cycloalkyl (C.sub.5 -C.sub.7) alkyl (C.sub.1 -C.sub.15) or a group --(Y.sub.2 --O).sub.m.sbsb.2 --R.sub.2,
- X is --O-- or --NR--,
- R is one of the significances of R.sub.6,
- R.sub.1 and R.sub.2 are, independently, hydrogen, phenyl, phenylalkyl (C.sub.7 -C.sub.22), phenyl or phenylalkyl substituted on the phenyl nucleus by --OH, alkyl or halogen and having up to 22 carbon atoms in the aggregate thereof, alkyl (C.sub.1 -C.sub.22), cycloalkyl (C.sub.5 -C.sub.7), alkyl (C.sub.1 -C.sub.15) cycloalkyl (C.sub.5 -C.sub.7), cycloalkyl (C.sub.5 -C.sub.7) alkyl (C.sub.1 -C.sub.15), alkyl (C.sub.1 -C.sub.15) cycloalkyl (C.sub.5 -C.sub.7) alkyl (C.sub.1 -C.sub.15), or a group ##SPC19##
- R.sub.3 is hydrogen, halogen, alkyl (C.sub.1 -C.sub.22), cycloalkyl (C.sub.5 -C.sub.7), cycloalkyl (C.sub.5 -C.sub.7) alkyl (C.sub.1 -C.sub.15), alkyl (C.sub.1 -C.sub.15) cycloalkyl (C.sub.5 -C.sub.7), alkyl (C.sub.1 -C.sub.15) cycloalkyl (C.sub.5 -C.sub.7) alkyl (C.sub.1 -C.sub.15), --CN, --COOR.sub.6, --SO.sub.3 R.sub.6, --OR.sub.6, --NHR.sub.6 or --N(R.sub.6).sub.2, --CO.sub.2 M, --SO.sub.3 M or a group --CO--X--(Y.sub.1 O).sub.m.sbsb.1 --R.sub.1,
- with the proviso that when R.sub.4 " or R.sub.5 " is a group --CO--X--(Y.sub.1 O).sub.m.sbsb.1 --R.sub.1, then R.sub.1 is hydrogen, or when R.sub.4 is a group O--(Y.sub.2 --O).sub.m.sbsb.2 --R.sub.2, then R.sub.2 is hydrogen,
- m.sub.1 and m.sub.2 are integers 1 to 100 , the sum of all the integers m.sub.1 and m.sub.2 being 1 to 100,
- and z.sub.1 and z.sub.2 are integers 1 to 100 , the sum of all the integers z.sub.1 and z.sub.2 being 5 to 100, and when relevant, the sum of all the integers z.sub.1 , z.sub.2, m.sub.1 and m.sub.2 being 6 to 100.
11 more elements
A compound of claim 3 of the formula, ##SPC22##
- wherein R.sub.7 is as defined in claim 11, and
- z.sub.1 '", z.sub.2 '", z.sub.3 '" and z.sub.4 '" are each an integer 1 to 17, the sum of z.sub.1 '", z.sub.2 '", z.sub.3 '" and z.sub.4 '" being 5 to 20.
A compound of the formula ##SPC24##
- wherein n.sub.1 '",n.sub.2 '",n.sub.3 '" and n.sub.4 '" are integers of 1 to 5, ther sum of n.sub.1 '",n.sub.2 '", n.sub.3 '" and n.sub.4 '" being
A compound of the formula ##SPC25##
- wherein n.sub.1.sup.IV, n.sub.2.sup.IV, n.sub.3.sup.IV and n.sub.4.sup.IV are integers 1 to 3, the sum of n.sub.1.sup.IV, n.sub.2.sup.IV,
Dependencies are inferred from the claim text.