Thiazole-azo dyes and the coloration of polyester textile fibers therewith
AssigneeAmerican Aniline Products, Inc.
InventorsEdgar Earl Renfrew, Henry Wolfgang Pons
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Abstract
Azo dyes for dyeing polyester fabric are made by coupling an appropriate diazotized amino heterocyclic base into an .alpha.-(N-alkylanilino)-m-toluene sulfonamide, typified by .alpha.-(N-ethyl anilino)-m-toluene sulfonamide. This class of azo dye, when appropriately dispersed, produces dyeings on aromatic polyester fabrics with excellent substantivity, outstanding sublimation fastness, and good fastness to light. The dyes are applied to polyesters, such as polyethylene terephthalate, by carrier dyeing, pressure dyeing, and thermofixation methods.
Claims8
Polyester dyed with a compound of the formula:
- ##SPC14##
- wherein B is selected from the group consisting of ##SPC15##
- wherein
- R.sub.7 is selected from the group consisting of hydrogen and methyl, and
- R.sub.8 and R.sub.9 are independently selected from a group consisting of hydrogen, lower alkyl, lower alkoxy, chloro, bromo, nitro, sulfamyl, N lower alkyl sulfamyl, N,N-(di-lower-alkyl)sulfamyl, cyano and lower alkyl sulfonyl;
- R.sub.1 is selected from the group consisting of lower alkyl, hydroxy lower alkyl, and cyano lower alkyl;
- R.sub.2, r.sub.3, and R.sub.4 are independently selected from the group consisting of hydrogen, lower alkyl, lower alkoxy, chlorine and bromine;
- and
- R.sub.5 and R.sub.6 are independently selected from the group consisting of hydrogen, lower alkyl, cyano lower alkyl and hydroxy lower alkyl.
Dependencies are inferred from the claim text.