Support structures for fixed bed flow reactors
AssigneeE. I. Du Pont de Nemours and Company
InventorJohn Joseph McBride
Life of this patent
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Abstract
A catalyst support is described for use in fixed bed flow reactors. The support is a porous, self-supporting structure of multiple layers of a yarn of partially sintered glass-ceramic fibers. The structure has diamond shaped apertures in its walls to provide good fluid permeability. Preferably, it is tubular. Coated with a catalyst, the structures are especially adapted for use in the catalytic conversion of pollutants in the exhaust fumes of internal combustion engines.
Claims13
A fluid permeable, refractory structure containing no more than 30% cristobalite and comprising:
- A. a plurality of layers of porous yarn, each layer having the yarn within it in spaced apart, substantially parallel rows, each layer being arranged in relationship with the neighboring layers such that a plurality of about diamond shaped apertures is defined by the criss-crossing of yarn in the neighboring layers, and each layer in the structure arranged such that the about diamond shaped apertures extend through the structure;
- said yarn consisting essentially of siliceous glass-ceramic fibers that are partially sintered and containing at least 60% of stable crystalline phases and comprising between about 20% and 85% of the structure, by weight and having a porosity of 10-70% and
- B. from about 15% to about 80% of the structure, by weight, of a ceramic coating of a polycrystalline oxide or oxide compound or mixtures thereof which is affixed and positioned to at least partially surround the fibers but which does not close the diamond shaped apertures;
- the crystalline phases and ceramic coating having melting points of at least 1400.degree.C.
The article of claim 13, wherein said fibers contain at least 40% by weight of silica, said coating is comprised of at least one refractory oxide and there is a reaction interface between the fibers and coating comprised of at last one polycrystalline refractory silicate.
As an article of manufacture, a rigid, self-supporting porous, refractory tube containing no more than 30% cristobalite, adapted to support a catalyst and characterized by a creep failure temperature above 1200.degree.C., said tube comprising:
- yarn arranged in crisscrossed layer of spaced, helical convolutions presenting multiple rows of apertures extending therethrough,
- said yarn being comprised of partially sintered, siliceous, glass-ceramic fibers containing at least 60% of stable crystalline phases bearing a ceramic coating of a polycrystalline oxide or oxide compound or mixtures thereof and wherein the yarn has a porosity of 10-70%.
Dependencies are inferred from the claim text.