Process for reacting a phenol with a vicinal epoxy compound in the presence of phosphorus or carbon containing acid, ester or acid ester
AssigneeThe Dow Chemical Company
InventorWilliam O. Perry
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Abstract
A process for the preparation of phenolic hydroxy ethers whereby an aromatic hydroxyl-containing compound is reacted with a vicinal epoxy-containing compound in the presence of a phosphonium salt of an acid, ester or acid ester of an element selected from carbon or phosphorus, and to precatalyzed epoxy resin compositions comprising an epoxy resin and a catalyst as defined above.
Claims20
In a process for preparing phenolic hydroxy ethers which comprises reacting a polyhydric phenol with a polyepoxide having more than one 1,2-epoxy group, the improvement comprising employing as the catalyst therefor, a phosphonium salt of an acid, ester or acid ester of the element carbon represented by the general formula ##EQU10## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently selected from the group consisting of aliphatic hydrocarbon radicals containing from about 1 to about 20 carbon atoms, aromatic hydrocarbon radicals, alkyl substituted aromatic hydrocarbon radicals and radicals represented by the formula -R.sub.5 Y wherein R.sub.5 is an aliphatic hydrocarbon radical having from about 1 to about 20 carbon atoms and Y is a member selected from the group consisting of Cl, Br, I, and NO.sub.2, and wherein X is the anion portion of an acid, ester or acid ester of the element carbon and wherein m is the valence of the anion X.
A process for preparing high molecular weight resins which comprises reacting a polyepoxide having an epoxy equivalency greater than 1.0 with a polyhydric phenol in the presence of from about 0.001 percent to about 10 percent by weight of the reactants of a hydrocarbon phosphonium acetate-acetic acid complex of the general formula ##EQU14## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and represent hydrocarbon radicals.
A process for preparing high molecular weight resins which comprises reacting a polyepoxide having an epoxy equivalency greater than 1.0 with a polyhydric phenol in the presence of from about 0.001 percent to about 10 percent by weight of the reactants of a hydrocarbon phosphonium acetate catalyst of the general formula ##EQU15## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and represent hydrocarbon radicals, and n has a value of zero or one.
Dependencies are inferred from the claim text.