Process for the manufacture of aromatic sulfonic acid halides
AssigneeHoechst Aktiengesellschaft
InventorsKurt Gengnagel, Theodor Papenfuhs, Manfred Zimmermann
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Abstract
An improved process for the manufacture of aromatic sulfonic acid halides from aromatic diazonium compounds, wherein aromatic diazonium compounds are reacted in a strongly hydrochloric or hydrobromic solution in the presence of copper or copper compounds with an alkali metal hydrogeno-sulfite, which avoids the use of liquid or gaseous sulfur dioxide and of organic solvents according to known processes which makes the process, if carried out on a technical scale, expensive and strongly contaminates the waste water.
Claims2
A process for the manufacture of aromatic sulfonic acid chlorides of the formula
- A -- SO.sub.2 Cl
- in which A is phenyl or phenyl substituted by a group or groups selected from alkyl of 1 to 4 carbon atoms, nitro, trifluoromethyl, carboxy, hydroxy, alkylsulfonyl of 1 to 4 carbon atoms, alkenylsulfonyl of 1 to 4 carbon atoms or halogen, or is naphthyl, which comprises reacting in an aqueous strongly hydrochloride solution in the absence of an organic solvent and in the presence of copper or copper compounds a diazonium compound of an aromatic amine of the formula
- A -- NH.sub.2
- wherein A is defined as above, with an alkali metal hydrogen sulfite.
Dependencies are inferred from the claim text.