Process for treatment of reaction mixtures by hydrogenation
AssigneeHalcon International, Inc.
InventorJohn Kollar
Life of this patent
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Abstract
The acidic catalyst characteristics of a reaction mixture resulting from a catalytic epoxidation are reduced whereby dehydration of by-product alcohol is suppressed during subsequent work-up procedures. This reduction is effected by catalytic hydrogenation, chemical reduction or the addition of a basic material.
Claims5
The process for treating the product mixture containing an alcohol from the epoxidation of an olefinic hydrocarbon having 2 to 30 carbon atoms with an organic hydroperoxide having the formula ROOH where R is an alkyl, cycloalkyl or carbocyclic aralkyl having 3 to 20 carbon atoms at a temperature of -20.degree. to 200.degree.C in the presence of a titanium, vanadium, chromium, selenium, zirconium, columbium, molybdenum, tellurium, tungsten, rhenium, or uranium catalyst, in order to reduce the acidic catalyst characteristics of said product mixture at least to the extent that the rate of dehydration of said alcohol contained therein is less than 50% per hour at 140.degree.C which comprises the step of hydrogenating said product mixture in the presence of a hydrogenation catalyst at a temperature in the range of 0.degree. to 150.degree.C and at a pressure of 14.7 to 100 psia.
The process for treating the product mixture containing an alcohol from the epoxidation of an olefinic hydrocarbon having 2 to 30 carbon atoms with an organic hydroperoxide having the formula ROOH where R is an alkyl, cycloalkyl or carbocyclic aralkyl having 3 to 20 carbon atoms at a temperature of -20.degree. to 200.degree.C in the presence of a titanium, vanadium, chromium, selenium, zirconium, columbium, molybdenum, tellurium, tantalum, tungsten, rhenium, or uranium catalyst, in order to reduce the acidic catalyst characteristics of said product mixture at least to the extent that the rate of dehydration of said alcohol contained therein is less than 50% per hour at 140.degree.C which comprises the step of hydrogenating said product mixture at a temperature in the range of 0.degree. to 150.degree.C in the presence of a hydrogenation catalyst selected from the group consisting of platinum, copper, nickel and zinc.
Dependencies are inferred from the claim text.