Metathesis of cycloolefins
AssigneeThe Goodyear Tire & Rubber Company
InventorEilert A. Ofstead
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Abstract
There is disclosed a new process for ring-opening polymerization of cycloolefins by the use of a catalyst comprising (A) tungsten or molybdenum halides, (B) alkyl aluminum halides and (C) an alcohol which has a nitrile substituent. Also the catalyst is disclosed as useful in metathesis of olefins.
Claims8
A cycloolefin metathesis process comprising polymerizing at least one unsaturated alicyclic compound selected from the group consisting of (1) unsaturated alicyclic compounds containing five carbon atoms in the ring and containing one double bond in the ring, (2) nonconjugated unsaturated alicyclic compounds containing at least seven carbon atoms in the ring and at least one double bond in the ring, and (3) polycyclic olefins and diolefins, by subjecting said alicyclic compounds or mixtures thereof to polymerization conditions in the presence of a catalyst system comprising (A) at least one transition metal salt selected from the group consisting of tungsten halides and tungsten oxyhalides, (B) at least one compound selected from the group consisting of alkylaluminum sesquihalides and alkylaluminum dihalides, and (C) at least one hydroxy compound of the general formula ROH wherein R is selected from the group consisting of alkyl and cycloalkyl and wherein R contains a nitrile substituent, wherein the molar ratio of A:B:C lies within the range of 1:0.5-10:0.5-3.
Dependencies are inferred from the claim text.