Polymers of N-aminoalkyl acrylamides
AssigneeThe Lubrizol Corporation
InventorDonald Irvin Hoke
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Abstract
N-3-Aminoalkyl propionamides with an ether substituent on the beta carbon atom are prepared by the reaction of analogous N-3-oxohydrocarbon-substituted amides with an amine in the presence of a reducing agent, preferably hydrogen and a hydrogenation catalyst. The resulting compounds can be converted to acrylamides by pyrolysis in the presence of a strong base. The latter compounds may also be prepared by the reaction of a .beta.,.gamma.-unsaturated amine with an acrylonitrile in the presence of sulfuric acid. They are useful for improving dyeability of fiber-forming polymers and may be polymerized to form compositions which are useful in paper manufacture and (in their quaternized form) are excellent flocculants.
Claims8
A polymer of a compound of the formula ##EQU22## wherein each of R.sup.1, R.sup.2 and R.sup.3 is hydrogen or a hydrocarbon radical;
- each of R.sup.4 and R.sup.5 is a hydrocarbon radical;
- R.sup.7 is hydrogen or a lower alkyl radical;
- and each of Z.sup.1 and Z.sup.2 is a lower alkyl or C.sub.3-8 cycloalkyl radical, or ##EQU23## is a heterocyclic radical.
Dependencies are inferred from the claim text.